Microplastic distribution and ecological risks: investigating road dust and stormwater runoff across land uses

Road dust and stormwater runoff are significant pathways for transporting microplastics (MPs) from land-based sources to the surrounding ecological compartments. The aim of this study is to understand the occurrence of MPs in both road dust and stormwater samples collected under various land uses, including residential, commercial and industrial areas, within Melbourne metropolitan city, Australia. This study also evaluated the ecological risk indices of MP polymers under different land uses. MP emission characteristics and loads (number- and mass-based) were estimated to investigate pollution risks. Higher quantities of MPs were detected in road dust and stormwater in industrial areas (2410 items per kg and 35 items per L) than in commercial (2130 items per kg and 27 items per L) and residential (1970 items per kg and 24 items per L) areas. Mass loads of MPs were also higher in industrial regions in road dust and stormwater samples. It was found that 200 mu m to 2450 mu m sized MPs were abundant in road dust, which was higher than the sizes of stormwater MPs (125 mu m to 960 mu m). The water forces in the drainage system could be the reason for the breakdown of larger MPs. Fragments and fibers were the dominant shapes of MPs in all the selected areas. Fourier transform infrared spectroscopy of representative samples identified several types of polymers, predominantly polypropylene, polyethylene, polyethylene terephthalate/polyester, polyvinyl chloride and polyethylene. The hazard index indicates that the ecological risks of MPs are higher in industrial areas than in other areas. This study revealed that MP emission via road dust was significantly higher due to traffic and industrial and human activities. This study has demonstrated that stormwater runoff is the primary corridor for transporting MPs from road dust to the aquatic environment of wetlands. This study in Melbourne, Australia, reveals higher levels of microplastic pollution in industrial areas compared to commercial or residential areas. Stormwater runoff is identified as the main pathway for transporting MPs from road dust to aquatic ecosystems.