Access to thioethers from thiols and alcohols via homogeneous and heterogeneous catalysis

被引:8
|
作者
Markwitz, Martyna [1 ]
Labrzycki, Klaudiusz [1 ]
Azcune, Laura [2 ]
Landa, Aitor [2 ]
Kucinski, Krzysztof [1 ]
机构
[1] Adam Mickiewicz Univ, Fac Chem, Uniwersytetu Poznanskiego St 8, PL-61614 Poznan, Poland
[2] Univ Basque Country UPV EHU, Fac Chem, Dept Organ Chem 1, Paseo Manuel Lardizabal 3, San Sebastian 20018, Spain
来源
SCIENTIFIC REPORTS | 2023年 / 13卷 / 01期
关键词
SELECTIVE HYDROTHIOLATION; HIGHLY EFFICIENT; TRIFLIC ACID; METAL; TERTIARY; ROUTE;
D O I
10.1038/s41598-023-47938-4
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
A metal-free dehydrative thioetherification method has been reported, enabling the conversion of various alcohols and thiols into thioethers. By employing triflic acid as a catalyst or utilizing a recyclable NAFION (R) superacid catalyst, these methods significantly improve the efficiency and practicality of sulfide preparation.
引用
收藏
页数:8
相关论文
共 50 条
  • [41] Catalysis at the Homogeneous-Heterogeneous Chemistry Interface
    Howard Alper
    复旦学报(自然科学版), 2007, (05) : 597 - 597
  • [42] The interface between heterogeneous and homogeneous catalysis - Preface
    Marks, TJ
    Stair, PC
    TOPICS IN CATALYSIS, 2005, 34 (1-4) : 1 - 1
  • [43] Beyond Relationships Between Homogeneous and Heterogeneous Catalysis
    David A. Dixon
    Alexander Katz
    Ilke Arslan
    Bruce C. Gates
    Catalysis Letters, 2014, 144 : 1785 - 1789
  • [44] Homogeneous and Heterogeneous Gold Catalysis for Materials Science
    Hendrich, Christoph M.
    Sekine, Kohei
    Koshikawa, Takumi
    Tanaka, Ken
    Hashmi, A. Stephen K.
    CHEMICAL REVIEWS, 2021, 121 (14) : 9113 - 9163
  • [45] π Activation of Alkynes in Homogeneous and Heterogeneous Gold Catalysis
    Bistoni, Giovanni
    Belanzoni, Paola
    Belpassi, Leonardo
    Tarantelli, Francesco
    JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (27): : 5239 - 5247
  • [46] Metal Catalysts Recycling and Heterogeneous/Homogeneous Catalysis
    Arai, Masahiko
    Zhao, Fengyu
    CATALYSTS, 2015, 5 (02): : 868 - 870
  • [47] α-Heteroarylation of Thioethers via Photoredox and Weak Bronsted Base Catalysis
    Alfonzo, Edwin
    Hande, Sudhir M.
    ORGANIC LETTERS, 2021, 23 (15) : 6115 - 6120
  • [48] Recent Advances for Alkylation of Ketones and Secondary Alcohols Using Alcohols in Homogeneous Catalysis
    Yang, Dong-Yuan
    Wang, Hongli
    Chang, Chun-Ran
    ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (18) : 3100 - 3121
  • [49] Hydroxymethylation of 2-methoxyphenol with formaldehyde to yield vanillic alcohols: A comparison between homogeneous and heterogeneous acid catalysis
    Ardizzi, M
    Cavani, F
    Dal Pozzo, L
    Maselli, L
    Catalysis of Organic Reactions, 2005, 104 : 357 - 361
  • [50] Combining advantages of homogeneous organocatalysis and heterogeneous catalysis with thermosensitive single-chain nanoparticles in a representative tetrahydropyranilation of alcohols
    Rumyantsev, Misha
    Rumyantsev, Sergey
    POLYMER, 2018, 136 : 101 - 108