Influences of ZrO2 content on microstructural and ionic conductivity of Li1.4Al0.4Ti1.6(PO4)3 solid-state electrolytes

被引：0

作者：

Li, Shuixian ^{[1
]}

Shang, Fei ^{[1
]}

Wang, Yi ^{[1
]}

Chen, Guohua ^{[1
,2
]}

机构：

[1] Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China

[2] Guilin Univ Elect Technol, Guangxi Key Lab Informat Mat, Guilin 541004, Peoples R China

来源：

SOLID STATE IONICS | 2024年 / 406卷

基金：

中国国家自然科学基金;

关键词：

Ceramics; Solid-state electrolytes; Ionic conductivity; Li1.4Al0.4Ti1.6(PO4)(3); ELECTRICAL-PROPERTIES; LITHIUM; MECHANISMS; CHROMIUM; ALUMINUM; SYSTEM;

D O I：

10.1016/j.ssi.2024.116460

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NASICON-type electrolyte Li1.4Al0.4Ti1.6(PO4)(3) attracts great attention with its high grain conductivity and stable microstructure. In this work, the Li1.4Al0.4Ti(1.6-x)Zrx(PO4)(3) solid-state electrolytes were synthetized. And the influences of ZrO2 addition on microstructural evaluation and ionic conductivity of Li1.4Al0.4Ti(1.6-x)Zrx(PO4)(3) were studied using powder X-ray diffraction, scanning electron microscopy and impedance spectroscopy. All synthetic samples adopted single phase LiTi2(PO4)(3) with NASICON type structure. The highest ionic conductivity of 0.54 mS/cm and the minimum activation energy of 0.232 eV were achieved for x = 0.04 sample sintered at 850 degrees C. These results indicate that ZrO2 added Li1.4Al0.4Ti1.6(PO4)(3) ceramic has a potential application in solid electrolytes.

引用

页数：9

共 50 条

[1] Influences of ZrO2 content on microstructural and ionic conductivity of Li1.4Al0.4Ti1.6(PO4)3 solid-state electrolytes
Li, Shuixian
Shang, Fei
Wang, Yi
Chen, Guohua
Solid State Ionics, 2024, 406
[2] Li1.4Al0.4Ti1.6(PO4)3 USED AS SOLID ELECTROLYTE FOR STRUCTURAL SUPERCAPACITORS
Liao, Guangyue
Geier, Sebastian
Mahrholz, Thorsten
Wierach, Peter
Wiedemann, Martin
ASME CONFERENCE ON SMART MATERIALS, ADAPTIVE STRUCTURES AND INTELLIGENT SYSTEMS, 2015, VOL 1, 2016,
[3] Preparation and characterization of Li1.4Al0.4Ti1.6(PO4)3 conducting electrolyte
Hamidi, Maziidah
Mohamed, Syafawati Nadiah
Ali, Abdul Malik Marwan
Winie, Tan
Yahya, Muhd Zu Azhan
IEEE SYMPOSIUM ON BUSINESS, ENGINEERING AND INDUSTRIAL APPLICATIONS (ISBEIA 2012), 2012, : 53 - 56
[4] Li1.4Al0.4Ti1.6(PO4)3 nanoparticle-reinforced solid polymer electrolytes for all-solid-state lithium batteries
Liu, Lehao
Chu, Lihua
Jiang, Bing
Li, Meicheng
SOLID STATE IONICS, 2019, 331 : 89 - 95
[5] Preparation, microstructure and electrical properties of Li1.4Al0.4Ti1.6(PO4)3 nanoceramics
Zhaoyin Wen
Xiaoxiong Xu
Jingxin Li
Journal of Electroceramics, 2009, 22 : 342 - 345
[6] Preparation, microstructure and electrical properties of Li1.4Al0.4Ti1.6(PO4)3 nanoceramics
Wen, Zhaoyin
Xu, Xiaoxiong
Li, Jingxin
JOURNAL OF ELECTROCERAMICS, 2009, 22 (1-3) : 342 - 345
[7] Interface stability between Li1.4Al0.4Ti1.6(PO4)3 and cathode for all solid-state lithium-ion batteries
Choi, Junbin
Yu, Chanyeop
Anandan, Venkataramani
Kim, Jung-Hyun
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[8] Lithium -ion conduction of Li1.4Al0.4Ti1.6(PO4)3-GeO2 composite solid electrolyte
Bai, Fan
Shang, Xuefu
Nemori, Hiroyoshi
Nomura, Masaya
Mori, Daisuke
Matsumoto, Mitsuhiro
Kyono, Nobuki
Takeda, Yasuo
Yamamoto, Osamu
Imanishi, Nobuyuki
SOLID STATE IONICS, 2019, 329 : 40 - 45
[9] High-Temperature Chemical Stability of Li1.4Al0.4Ti1.6(PO4)3 Solid Electrolyte with Various Cathode Materials for Solid-State Batteries
Yu, Chan-Yeop
Choi, Junbin
Anandan, Venkataramani
Kim, Jung-Hyun
JOURNAL OF PHYSICAL CHEMISTRY C, 2020, 124 (28): : 14963 - 14971
[10] Exploring Li-CO2 batteries with electrospun PAN-derived carbon nanofibers and Li1.4Al0.4Ti1.6(PO4)3 solid-state electrolyte
Na, Dan
Kampara, Roopa Kishore
Yu, Dohyeon
Yoon, Baeksang
Lee, Dae Young
Seo, Inseok
JOURNAL OF ALLOYS AND COMPOUNDS, 2024, 970

← 1 2 3 4 5 →