New triterpenoid saponins from the stem bark of Hallea ledermannii

被引:1
|
作者
Koffi, Jean-Michel Kouame [1 ]
Yao-Kouassi, Philomene Akoua [1 ,3 ]
Magid, Abdulmagid Alabdul [2 ]
Akissi, Zachee Louis Evariste [1 ,2 ]
Martinez, Agathe [2 ]
Sayagh, Charlotte [2 ]
Voutquenne-Nazabadioko, Laurence [2 ]
机构
[1] Univ Felix Houphouet Boigny, Lab Constitut & React Matiere, UFR Sci Struct Matiere & Technol, 22 BP 582, Abidjan, Cote Ivoire
[2] Univ Reims, Inst Chim Mol Reims ICMR, CNRS, Chim Subst Nat,UMR 7312, F-51097 Reims, France
[3] Univ San Pedro, BP V1800, San Pedro, Cote Ivoire
关键词
Hallea ledermannii; Rubiaceae; Triterpenoid saponins; QUINOVIC ACID GLYCOSIDES;
D O I
10.1016/j.tetlet.2022.154335
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Twenty-three triterpenoid saponins (1-23) have been isolated from the aquoeus and ethyl acetate frac-tions of the stem bark of Hallea ledermannii. Among them, nine (1-9) are newly described, some of them containes uncommun natural 6-deoxy-D-allofuranose, 6-deoxy-D-allopyranose, and 6-deoxy-D-pyranose as a sugar moiety. This is the first report of the isolation and structural elucidation of these compounds from H. ledermannii. The chemical structure of the compounds was determined using NMR and HRMS data. (c) 2022 Elsevier Ltd. All rights reserved.
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页数:7
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