Selective hydrogenation of amides and imides over heterogeneous Pt-based catalysts

被引：1

作者：

Qu, Ruiyang ^{[1
]}

Mao, Shuxin ^{[1
]}

Weiss, Jana ^{[1
]}

Kondratenko, Vita A. ^{[1
]}

Kondratenko, Evgenii V. ^{[1
]}

Bartling, Stephan ^{[1
]}

Qi, Haifeng ^{[1
]}

Surkus, Annette-Enrica ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Leibniz Inst Katalyse EV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2024年 / 14卷 / 01期

关键词：

AMINES;

D O I：

10.1039/d3cy01274c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation of amides is an important but highly challenging reaction, which usually is applied under drastic conditions (temperature >160 degree celsius). Here, we report a heterogeneous Pt-MoOx/TiO2 catalyst for amide and imide hydrogenation under milder conditions. The catalytic reactivity is proposed to originate from the synergistic effect between surface active species. Pt promotes formation of partially reduced MoOx that is responsible for C=O activation, and MoOx-modified Pt can more efficiently generate surface species from gas-phase H-2. This catalyst system enables the selective hydrogenation of several 2(degrees) and 3(degrees) amides as well as imides.

引用

页码：90 / 97

页数：8

共 50 条

[21] Towards the continuous production of Pt-based heterogeneous catalysts using microfluidic systems
Laura, Uson
Arruebo, Manuel
Sebastian, Victor
DALTON TRANSACTIONS, 2018, 47 (05) : 1693 - 1702
[22] Carbon Deposition on Heterogeneous Pt Catalysts Promotes the Selective Hydrogenation of Halogenated Nitroaromatics
Li, Kaijia
Qin, Ruixuan
Liu, Kunlong
Zhou, Wenting
Liu, Ning
Zhang, Yazhou
Liu, Shengjie
Chen, Jie
Fu, Gang
Zheng, Nanfeng
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (44) : 52193 - 52201
[23] Geometric and electronic effects on hydrogenation of cinnamaldehyde over unsupported Pt-based nanocrystals
Oduro, William O.
Cailuo, Nick
Yu, Kai Man K.
Yang, Hongwei
Tsang, Shik Chi
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (07) : 2590 - 2602
[24] Effect of amino-defective-MOF materials on the selective hydrodeoxygenation of fatty acid over Pt-based catalysts
Phan, Dieu-Phuong
Le, Van Nhieu
Ha Nguyen, Thuy
Kim, Han Bom
Park, Eun Duck
Kim, Jinsoo
Lee, Eun Yeol
JOURNAL OF CATALYSIS, 2021, 400 : 283 - 293
[25] Hydrogenation of heptanal over heterogeneous catalysts
Greish, Alexander A.
Kustov, Leonid M.
Shuvalova, Elena V.
Kirichenko, Olga A.
MENDELEEV COMMUNICATIONS, 2013, 23 (04) : 219 - 221
[26] Selective hydrogenation of amides using Rh/Mo catalysts
Beamson, Graham
Papworth, Adam J.
Philipps, Charles
Smith, Andrew M.
Whyman, Robin
JOURNAL OF CATALYSIS, 2010, 269 (01) : 93 - 102
[27] Selective combustion of hydrogen in the presence of hydrocarbons -: 1.: Pt-based catalysts
Låte, L
Rundereim, JI
Blekkan, EA
APPLIED CATALYSIS A-GENERAL, 2004, 262 (01) : 53 - 61
[28] Selective Hydrogenation of Amides using Ruthenium/Molybdenum Catalysts
Beamson, Graham
Papworth, Adam J.
Philipps, Charles
Smith, Andrew M.
Whyman, Robin
ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (05) : 869 - 883
[29] Bimass derived acetic acid hydrodeoxygenation over Pt-based bimetallic catalysts
Zheng, Yiteng
Podkolzin, Simon
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
[30] Steam reforming of ethanol to produce hydrogen over Cu and Pt-based catalysts
Ji, C.-W. (chwji@bjut.edu.cn), 1600, Beijing University of Technology (38):

← 1 2 3 4 5 →