Heterocyclic Boron Acid Catalyzed Dehydrative Amidation of Aliphatic/Aromatic Carboxylic Acids with Amines

被引：25
|
作者：
Pan, Bin [2 ]
Huang, Ding-Min [3 ]
Sun, Hao-Tian [3 ]
Song, Sheng-Nan [3 ]
Su, Xian-Bin [1 ]
机构：
[1] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China
[2] Weifang Univ Sci & Technol, Shandong Peninsula Engn Res Ctr Comprehens Brine U, Weifang 262700, Peoples R China
[3] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 05期
关键词：
DIRECT AMIDE FORMATION; PEPTIDE-BOND FORMATION; MECHANISTIC INSIGHTS; CONDENSATION; EFFICIENT; PALLADIUM; TRANSAMIDATION; ACTIVATION; ALDEHYDES; CARBON;
D O I：
10.1021/acs.joc.2c02515
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A commercially available and versatile dehydrative amidation catalyst, featuring a thianthrene boron acid structure, has been developed. The catalyst shows high catalytic activity to both aliphatic and less reactive aromatic carboxylic acid substrates, including several bioactive or clinical molecules with a carboxylic acid group.
引用
收藏
页码：2832 / 2840
页数：9
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