Dimension-Dependent Phase Transitions, Ferroelasticity, and Photoluminescence in Hybrid Organic-Inorganic Materials

被引：7
|
作者：
Cao, Peng [1 ,2 ]
Liu, Yu-Ting [1 ,2 ]
Men, Jin-Tao [1 ,2 ]
Zheng, Xuan [1 ,2 ]
Zhang, Wen [1 ,2 ]
He, Lei [1 ,2 ]
Ye, Qiong [1 ,2 ]
机构：
[1] Southeast Univ, Jiangsu Key Lab Sci & Applicat Mol Ferroelect, Nanjing 211189, Peoples R China
[2] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
INORGANIC CHEMISTRY | 2023年 / 62卷 / 41期
关键词：
SEMICONDUCTORS; VACANCIES; COMPOUND;
D O I：
10.1021/acs.inorgchem.3c02560
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[(CH3)(3)P(CH2)(2)OH](2)Cd-3(SCN)(8) (1) and [(CH3)(3)P(CH2)(2)OH]Cd(SCN)(3) (2) were obtained with completely different structures and properties under the same synthesis conditions. Compound 1, showing green fluorescence, has a rare three-dimensional 4,6-connected fsh topology having (4(3).6(3))(2)(4(6).6(6).8(3)) Schla''fli notation, while compound 2 with blue-violet phosphorescence displays a one-dimensional perovskite structure with an infinite {[Cd(SCN)(3)](-)}(infinity) chain and exhibits both ferroelastic and dielectric switching characteristics.
引用
收藏
页码：16898 / 16904
页数：7
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