Facile synthesis of quinoxaline catalyzed by iron-based carbon material in water

被引：2

作者：

Zhu, Fuying ^{[1
,2
]}

Lin, Yamei ^{[1
,2
]}

机构：

[1] Nanjing Forestry Univ, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China

[2] Nanjing Normal Univ, Sch Food Sci & Pharmaceut Engn, Nanjing 210023, Peoples R China

来源：

TETRAHEDRON | 2024年 / 150卷

基金：

中国国家自然科学基金;

关键词：

Iron-based carbon material; Quinoxaline; Styrene oxide; Water; Heterogeneous catalysis; FUNCTIONALIZED QUINOXALINES; DERIVATIVES; NANOPARTICLES; BIOMASS; CONDENSATION; OXIDATION;

D O I：

10.1016/j.tet.2023.133752

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Herein, we report a low-metal iron-supported (0.06 wt%) catalyst (Fe20/NC-Mg), in which the FeNx site and Mg (OH)2 nanorods are synergistic to achieve the efficient synthesis of quinoxaline (16 examples, 82-91 % yield) with water as a solvent and without additional bases. Moreover, the industrial application potential of Fe20/NCMg is demonstrated by gram-level synthesis and reusability of catalysts after four cycles. This protocol has high atomic and step economy, which meets with the requirement of green synthesis.

引用

页数：6

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