One-Dimensional Copper(II) Coordination Polymer Based on 1,2-bis-(4-Pyridyl) Ethane and 1,10-Phenathroline

被引：1
|
作者：
Kawade, Vitthal A. [1 ]
Bhat, Satish S. [2 ]
Naveen, S. [3 ]
Lokanath, N. K. [4 ]
Butcher, R. J. [5 ]
机构：
[1] Ahmednagar Coll, Dr John Barnabas PG Sch Biol Studies, Dept Chem, Ahmednagar, Maharashtra, India
[2] Karnatak Univ, Dept Chem, Dharwad, Karnatak, India
[3] Jain Univ, Sch Engn & Technol, Dept Phys, Bangalore, India
[4] Univ Mysore, Dept Studies Phys, Mysuru, Karnataka, India
[5] Howard Univ, Dept Chem, Washington, DC USA
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2023年 / 64卷 / 07期
关键词：
copper(II) coordination polymer; hydrogen bonding; 1; 10-phenanthroline; bridging ligand; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; RATIONAL CONSTRUCTION; COMPLEXES; ADSORPTION; 4,4'-BIPYRIDINE; BEHAVIOR;
D O I：
10.1134/S002247662307017X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The one dimensional copper(II) coordination polymer {[Cu(phen)(bpe)(NO3)(H2O)](NO3)(H2O)}(n) (1) has been synthesized using [Cu(phen)(2)(NO3)(2)] (where phen = 1 & PRIME;10-phenanthroline and linker bpe = 1,2-bis-(4-pyridyl) ethane. Complex 1 was characterised by using elemental analysis, IR spectroscopy and single crystal X-ray diffraction analysis. The copper(II) ion is octahedrally coordinated with two nitrogen donor atoms from two bpe, two nitrogen donor atoms from phen, one oxygen donor atom from water and one oxygen donor atom from nitrato. Each 1D polymeric chain is connected to another chain via hydrogen bonding and p horizontal ellipsis p stacking interaction to form 3D network structures.
引用
收藏
页码：1341 / 1349
页数：9
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