Recent developments in nickel-catalyzed asymmetric cyclization and cycloaddition of carbonyl-alkynes, cyano-alkynes, and enynes

被引：2

作者：

Yan, Jun ^{[1
,2
]}

Shi, Min ^{[1
,2
,3
]}

Wei, Yin ^{[3
]}

机构：

[1] East China Univ Sci & Technol, Sch Chem & Mol Engn, Key Lab Adv Mat, 130 Meilong Rd, Shanghai 200237, Peoples R China

[2] East China Univ Sci andTechnol, Inst Fine Chem, Sch Chem& Mol Engn, 130 Meilong Rd, Shanghai 200237, Peoples R China

[3] Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Chinese Acad Sci, Ctr Excellence Mol Synth, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 30期

基金：

中国国家自然科学基金;

关键词：

C-H BOND; FORMAL TOTAL-SYNTHESIS; REDUCTIVE CYCLIZATION; ACTIVATION; ANNULATION; NITRILES; ACCESS; CASCADE; IMINES; CONSTRUCTION;

D O I：

10.1039/d3cc00520h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkynes as unsaturated hydrocarbons have long been used for cyclization reactions. Various transition metal-catalyzed cyclizations of alkynes have been reported in the past decades. In this minireview, we mainly summarize the recent asymmetric cyclization of alkynes with other functional groups such as carbonyl-alkynes, cyano-alkynes, and enynes under the catalytic system of nickel and chiral ligands.

引用

页码：4405 / 4422

页数：18

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