Covalent Organic Frameworks as Single-Site Photocatalysts for Solar-to-Fuel Conversion

被引：26

作者：

Yao, Liang ^{[1
,2
]}

Puetz, Alexander M. ^{[1
,3
]}

Vignolo-Gonzalez, Hugo ^{[1
,3
]}

Lotsch, Bettina V. ^{[1
,3
,4
,5
]}

机构：

[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

[2] South China Univ Technol, Inst Polymer Optoelect Mat & Devices, State Key Lab Luminescent Mat & Devices, Guangzhou 510640, Peoples R China

[3] Univ Munich LMU, Dept Chem, D-81377 Munich, Germany

[4] E Convers, D-85748 Munich, Germany

[5] Ctr Nanosci, D-85748 Munich, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2024年 / 146卷 / 14期

关键词：

SELECTIVE PHOTOREDUCTION; HYDROGEN-PRODUCTION; COBALT COMPLEXES; H-2; EVOLUTION; NI SITES; CATALYSTS; REDUCTION; CRYSTALLINE; ENERGY; ATOM;

D O I：

10.1021/jacs.3c11539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-site photocatalysts (SSPCs) are well-established as potent platforms for designing innovative materials to accomplish direct solar-to-fuel conversion. Compared to classical inorganic porous materials, such as zeolites and silica, covalent organic frameworks (COFs)-an emerging class of porous polymers that combine high surface areas, structural diversity, and chemical stability-are attractive candidates for SSPCs due to their molecular-level precision and intrinsic light harvesting ability, both amenable to structural engineering. In this Perspective, we summarize the design concepts and state-of-the-art strategies for the construction of COF SSPCs, and we review the development of COF SSPCs and their applications in solar-to-fuel conversion from their inception. Underlying pitfalls concerning photocatalytic characterization are discussed, and perspectives for the future development of this burgeoning field are given.

引用

页码：9479 / 9492

页数：14

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