Recent advancement in the synthesis and applications of N-acyl benzotriazoles in organic synthesis

被引：3

作者：

Zhu, Riqian ^{[1
]}

Li, Yang ^{[1
]}

Pan, Mengni ^{[1
]}

Shen, Yue ^{[1
]}

Li, Wanfang ^{[1
]}

机构：

[1] Univ Shanghai Sci & Technol, Sch Mat & Chem, Shanghai 200093, Peoples R China

来源：

TETRAHEDRON | 2023年 / 145卷

基金：

中国国家自然科学基金;

关键词：

N-acyl benzotriazoles; Acylation; Denitrogenative coupling; Visible-light photocatalysis; Heterocycle synthesis; CARBON BOND FORMATION; ONE-POT SYNTHESIS; BETA-KETO-ESTERS; EFFICIENT SYNTHESIS; CARBOXYLIC-ACIDS; EN-ROUTE; MEDIATED SYNTHESIS; SOFT ENOLIZATION; RING-CLEAVAGE; ACYLBENZOTRIAZOLES;

D O I：

10.1016/j.tet.2023.133608

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzotriazole is an important heterocyclic compound in pharmaceutical and material chemistry, its derivatives have found wide applications for synthetic organic chemistry. N-Acyl benzotriazoles are stable and easy to prepare and employed as mild and selective acylation reagents for N-, O-, S-and C-nucleophiles. This review summarized the recent developments in the following respects: 1) New synthetic methods for N-acyl benzo-triazoles; 2) Recent applications of N-acyl benzotriazole derivatives in the acylation reactions to solve some tough synthetic problems; 3) N-acyl benzotriazoles in denitrogenative transformations; 4) N-acyl benzotriazoles in radical and photoredox reactions; and other uncommon synthetic transformations with N-acyl benzotriazoles.

引用

页数：19

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