Palladium-Catalyzed E-Selective Oxidative Amination of Aromatic Amine with 3-Butenoic Acid

被引：5
|
作者：
Liu, Qianqian [1 ]
Zhou, Zheng [1 ]
Huang, Zhibin [1 ]
Zhao, Yingsheng [1 ,2 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[2] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453000, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 21期
关键词：
ALKENYL CARBONYL-COMPOUNDS; WACKER CYCLIZATION; ABUSE; AIR;
D O I：
10.1021/acs.joc.3c01843
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium-catalyzed oxidative amination of inactive olefins with an aromatic amine was developed using a copper acetate oxidant to yield corresponding secondary and tertiary enamines in moderate to good yields. This new procedure outlines an efficient approach for the construction of enamine skeletons.
引用
收藏
页码：15350 / 15357
页数：8
相关论文
共 50 条
  • [41] Efficient palladium-catalyzed amination and alkylation of 3-iodo-6-arylpyridazines
    Parrot, I
    Ritter, G
    Wermuth, CG
    Hibert, M
    SYNLETT, 2002, (07) : 1123 - 1127
  • [42] A NEW, PALLADIUM-CATALYZED SYNTHESIS OF AROMATIC MERCAPTURIC ACID-DERIVATIVES
    CIATTINI, PG
    MORERA, E
    ORTAR, G
    TETRAHEDRON LETTERS, 1995, 36 (23) : 4133 - 4136
  • [43] Palladium-Catalyzed Synthesis of Aromatic Ketones and Isoindolobenzimidazoles via Selective Aromatic CH Bond Acylation
    Lu, Juyou
    Zhang, Hao
    Chen, Xiaowu
    Liu, Hongxia
    Jiang, Yuyang
    Fu, Hua
    ADVANCED SYNTHESIS & CATALYSIS, 2013, 355 (2-3) : 529 - 536
  • [44] Palladium-catalyzed Selective Amination of Aryl(haloaryl)amines with 9H-Carbazole Derivatives
    Ohtsuka, Yuhki
    Yamamoto, Tetsuya
    Miyazaki, Takanori
    Yamakawa, Tetsu
    ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (05) : 1007 - 1018
  • [45] Access to -Amino Acid Esters through Palladium-Catalyzed Oxidative Amination of Vinyl Ethers with Hydrogen Peroxide as the Oxidant and Oxygen Source
    Ouyang, Lu
    Li, Jianxiao
    Zheng, Jia
    Huang, Jiuzhong
    Qi, Chaorong
    Wu, Wanqing
    Jiang, Huanfeng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (50) : 15926 - 15930
  • [46] Remarkably selective palladium-catalyzed amination process: Rapid assembly of multiamino based structures.
    Hong, YP
    Senanayake, CH
    Xiang, TJ
    Vandenbossche, CP
    Tanoury, GJ
    Bakale, RP
    Wald, SA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U507 - U507
  • [47] Palladium-catalyzed selective carbonylation of (E)-1,2-diidoalkenes
    Li, JH
    Tang, S
    SYNTHETIC COMMUNICATIONS, 2005, 35 (01) : 105 - 113
  • [48] Palladium-catalyzed α-regioselective allylic amination of Morita-Baylis-Hillman acetates with simple aromatic amines
    Wang, Yan
    Liu, Li
    Wang, Dong
    Chen, Yong-Jun
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (34) : 6908 - 6913
  • [49] Tetraazacyclophanes by palladium-catalyzed aromatic amination. Geometrically defined, stable, high-spin diradicals
    Hauck, SI
    Lakshmi, KV
    Hartwig, JF
    ORGANIC LETTERS, 1999, 1 (13) : 2057 - 2060
  • [50] Palladium-Catalyzed Z-Selective Oxidative Amination of ortho-Substituted Primary Anilines with Olefins under an Open Air Atmosphere
    Mizuta, Yohei
    Yasuda, Kaoru
    Obora, Yasushi
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (12): : 6332 - 6337
12345