Cost-effective smartphone-based method for low range chemical oxygen demand analysis *

被引:1
|
作者
Segundo, Inalmar D. Barbosa [1 ]
Cardozo, Jussara C. [1 ]
Castro, Pollyana Souza [2 ]
Gondim, Amanda D. [1 ,2 ]
dos Santos, Elisama V. [1 ,3 ]
Martinez-Huitle, Carlos A. [1 ,2 ,3 ,4 ]
机构
[1] Univ Fed Rio Grande do Norte, Inst Chem, Renewable Energies & Environm Sustainabil Res Grp, Ave Salgado Filho 3000,Campus Univ, BR-59078970 Lagoa Nova, Natal, Brazil
[2] Univ Fed Rio Grande do Norte, Inst Chem, Ave Salgado Filho 3000, BR-59078970 Lagoa Nova, Natal, Brazil
[3] UNESP, Natl Inst Alternat Technol Detect, Inst Chem, Toxicol Evaluat & Removal Mi cropollutants & Radio, POB 355, BR-14800900 Araraquara, SP, Brazil
[4] Fed Univ Grande Norte, Inst Chem, Renewable Energies & Environm Sustainabil Res Grp, Ave Salgado Filho 3000,Campus Univ, BR-59078970 Lagoa Nova, Natal, Brazil
基金
巴西圣保罗研究基金会;
关键词
COD; Smartphone-based technology; HSV image processing; Digital image colorimetry;
D O I
10.1016/j.mex.2023.102300
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Aiming the decentralization of monitoring policies and to facilitate the work of researchers, mainly in developing countries, the present method deals with the explanation of a simple and rapid protocol for chemical oxygen demand (COD) analysis through the use of digital smartphone devices coupled with a camera and a free app available for Android operating system that recog-nizes HSV (hue, saturation, value). The calibration of the method is done based on the theoretical values of potassium hydrogen phthalate for a proper and reliable build of the calibration curve by using the smartphone-based technique and the digested samples of COD. The coefficient of determination (R 2 ) attained a value upper than 0.99, providing a high confidence levels, and the method achieved 97% of average accuracy in samples with COD values ranging from 0 to 150 mg L -1. Finally, the procedure here presented can be a great support for scientific laboratories and monitoring policies, once it can efficiently substitute expensive spectrophotometers and can im-prove and ensure the sustainable management of water sanitation, which is one of the sustainable goals proposed by the United Nations. & BULL; COD measurements, based on the use of a simple smartphone with a camera, can be a promis-ing way for environmental analysis when spectrophotometers are not available, such as de-centralized approaches. & BULL; The use of smartphone protocol is a novel initiative to fulfill sustainable development goal 6 on clean water and sanitation. & BULL; The smartphone is capable to read the difference of HSV values efficiently and can substitute the use of expensive spectrophotometers.
引用
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页数:6
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