Reactivity of New Monomers of the Polyurethanes Green Chemistry, the Reaction Mechanism, and the Medium Effect

被引：2

作者：

Zabalov, M. V. ^{[1
]}

Levina, M. A. ^{[1
]}

Krasheninnikov, V. G. ^{[1
]}

Tiger, R. P. ^{[1
]}

机构：

[1] Russian Acad Sci, Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia

来源：

POLYMER SCIENCE SERIES B | 2023年 / 65卷 / 04期

关键词：

DIMETHYL-SULFOXIDE; CYCLIC CARBONATES; URETHANE FORMATION; HYDROGEN-BONDS; SUPERMOLECULE METHOD; ETHYLENE CARBONATE; OIL TRIGLYCERIDES; METHYL-GROUPS; FREE ROUTES; BLUE-SHIFT;

D O I：

10.1134/S1560090423701063

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of the substituents inductive effect and the proton-donor OH group in the substituted cyclocarbonates differing in the alkyl chain length on the activation barrier of their aminolysis reaction, which underlies the process of urethane formation without the participation of isocyanates, has been studied. Account for the solvent molecules has allowed quantitative interpretation of the process regularities. Kinetics of the model aminolysis reaction of a series of monomers in DMSO has been investigated.

引用

页码：467 / 474

页数：8

共 50 条

[41] NUCLEOPHILIC REACTIVITY OF ORGANOPHOSPHORUS COMPOUNDS .3. KINETICS AND MECHANISM OF REACTION OF PHOSPHORUS ACIDS WITH KETEN OO-ACETALS IN APROTIC MEDIUM
DYER, RL
LEGRAS, PG
HALL, CD
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (14): : 1613 - 1617
[42] Kinetic Study on Aminolysis of 4-Nitrophenyl Isonicotinate in Acetonitrile: Effect of Amine Basicity on Reactivity and Reaction Mechanism
Shin, Minah
Kim, Min-Young
Um, Ik-Hwan
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2014, 35 (07): : 2130 - 2134
[43] Medium effect (water versus MeCN) on reactivity and reaction pathways for the SNAr reaction of 1-aryloxy-2,4-dinitrobenzenes with cyclic secondary amines
Um, Ik-Hwan
Kim, Min-Young
Dust, Julian M.
CANADIAN JOURNAL OF CHEMISTRY, 2017, 95 (12) : 1273 - 1279
[44] Kinetics and Reaction Mechanism of Aminolyses of Benzyl 2-Pyridyl Carbonate and t-Butyl 2-Pyridyl Carbonate: Effect of Nonleaving Group on Reactivity and Reaction Mechanism
Kang, Ji-Sun
Lee, Jae-In
Um, Ik-Hwan
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (05) : 1551 - 1555
[45] New insights into the reactivity of aminomethylene derivatives of resorc[4]arene: amine group transfer, conformational analysis, reaction mechanism
Iwanek, Waldemar
RSC ADVANCES, 2022, 12 (42) : 27370 - 27379
[46] A green reaction-based turn-off fluorescence sensor for determination of copper ions: DFT calculations, quenching mechanism, green chemistry metrics, and application in environmental samples
Wang, Jian
Chen, Ling
Li, Yanan
Manley-Harris, Merilyn
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2024, 416 (14) : 3433 - 3445
[47] Green chemistry approach to the synthesis of 2-amino-4-aryl-6-ferrocenyl-pyridine derivatives by a one-pot reaction in aqueous medium
Zhuang, Qiya
Jia, Runhong
Tu, Shujiang
Zhang, Junyong
Jiang, Bo
Zhang, Yan
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2007, 44 (04) : 895 - 900
[48] Glycerol as Reaction Medium for Sonogashira Couplings: A Green Approach for the Synthesis of New Triarylamine-Based Materials with Potential Application in Optoelectronics
Raglione, Venanzio
Palmeri, Federica
Mattioli, Giuseppe
Porcelli, Francesco
Caschera, Daniela
Zanotti, Gloria
CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (68)
[49] Kinetic Study on Aminolysis of 4-Pyridyl X-Substituted Benzoates: Effect of Substituent X on Reactivity and Reaction Mechanism
Lee, Jong Pal
Bae, Ae Ri
Um, Ik-Hwan
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (06): : 1907 - 1911
[50] Kinetic Study on SNAr Reaction of 1-Y-Substituted-phenoxy-2,4-dinitrobenzenes with Hydroxide Ion: Effect of Substituent Y on Reactivity and Reaction Mechanism
Kang, Tae-Ah
Cho, Hyo-Jin
Um, Ik-Hwan
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2014, 35 (07) : 2135 - 2138

← 1 2 3 4 5 →