Enhanced electrochemical performance of CoMoO4 nanorods/reduced graphene oxide (rGO) as asymmetric supercapacitor devices

被引:11
|
作者
Nandagopal, T. [1 ]
Balaji, G. [1 ]
Vadivel, S. [2 ]
机构
[1] Paavai Engn Coll Autonomous, Dept Elect & Elect Engn, Namakkal 637018, Tamilnadu, India
[2] Saveetha Inst Med & Tech Sci SIMATS, Saveetha Sch Engn, Dept Phys, Chennai 602105, Tamil Nadu, India
关键词
CoMoO4; Hydrothermal; rGO; Supercapacitor energy storage device; ELECTRODE; CAPACITANCE; MECHANISM; ARRAYS; ANODE;
D O I
10.1016/j.est.2023.107710
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The efficiency of a supercapacitor depends heavily on the materials used to create its electrodes. Physicochemical properties have piqued interest in using transition metal molybdates as electrode materials in supercapacitors. Monodisperse CoMoO4 nanorods with a modest dimension (about 40-60 nm in width and 1.5-2 lim in length) were created on reduced graphene oxide (rGO) nanosheets were synthesized via a facile hydrothermal method. Hybrid CoMoO4@rGO electrodes have shown exceptional electrochemical properties, especially when compared to pure CoMoO4 in an alkaline electrolyte. In particular, the maximum specific capacitance of CoMoO4@rGO is 1425 Fg- 1 at a current density of 1Ag-1, while the greatest specific capacitance of CoMoO4 is 751 Fg- 1 at the same current density. Both the pure and hybrid electrodes show excellent rate capability and long-term cyclic stability, even at high current densities of 20 Ag-1. Also, at a current density of 20 Ag-1, the constructed asymmetric supercapacitor generated a maximum power density of 4.5 kWkg-1, and at a current density of 1 Ag-1, it generated a high energy density of 51.2 Whkg-1. Based on their promising electrochemical performance, the hierarchical CoMoO4@rGO nanocomposites were discovered to provide for a promising electrode material in the creation of highly effective supercapacitors for power storage.
引用
收藏
页数:8
相关论文
共 50 条
  • [21] Synergistic effects of nanocarbon spheres sheathed on a binderless CoMoO4 electrode for high-performance asymmetric supercapacitor
    Bhattarai, Roshan Mangal
    Pandiyarajan, Sudhakaran Moopri Singer
    Saud, Shirjana
    Kim, Sang Jae
    Mok, Young Sun
    DALTON TRANSACTIONS, 2020, 49 (41) : 14506 - 14519
  • [22] Fast and large lithium storages from CoMoO4 nanorods-graphene composite
    Jinxue Guo
    Haifeng Zhu
    Shaoqian Zhou
    Yanfang Sun
    Xiao Zhang
    Ionics, 2015, 21 : 2993 - 2999
  • [23] Electrodeposition of Manganese (III) Phthalocyanine/Reduced Graphene Oxide for Asymmetric Supercapacitor Devices
    Yenilmez, Hacer Yasemin
    Ozturk, Nazli Farajzadeh
    Budak, Ozlem
    Oney, Ozlem Ipsiz
    Koca, Atif
    Bayir, Zehra Altuntas
    CHEMISTRY-AN ASIAN JOURNAL, 2024, 19 (24)
  • [24] Self-assembling of Interconnected strips of CoMoO4 on Graphene sheet as Supercapacitor Electrodes
    Singh, Arvind
    Ojha, Animesh K.
    DAE SOLID STATE PHYSICS SYMPOSIUM 2019, 2020, 2265
  • [25] Electrodeposition of Manganese (III) Phthalocyanine/ Reduced Graphene Oxide for Asymmetric Supercapacitor Devices
    Yenilmez, Hacer Yasemin
    Ozturk, Nazli Farajzadeh
    Budak, Ozlem
    Oney, Ozlem Ipsiz
    Koca, Atif
    Bayir, Zehra Altuntas
    CHEMISTRY-AN ASIAN JOURNAL, 2024,
  • [26] Influence of heat-treatment temperature on the improvement of the electrochemical performance of CoMoO4 nanomaterials for hybrid supercapacitor application
    Sivakumar, Periyasamy
    Raj, C. Justin
    Ramesh, R.
    Kulandaivel, Loganathan
    Park, JeongWon
    Jung, Hyun
    CERAMICS INTERNATIONAL, 2022, 48 (19) : 29018 - 29024
  • [27] Facile and controlled synthesis of bismuth sulfide nanorods-reduced graphene oxide composites with enhanced supercapacitor performance
    Nie, Guangdi
    Lu, Xiaofeng
    Lei, Junyu
    Yang, Liu
    Wang, Ce
    ELECTROCHIMICA ACTA, 2015, 154 : 24 - 30
  • [28] Symmetric supercapacitor based on biosynthesized nanosheets of reduced graphene oxide (rGO): Characterization and electrochemical behavior
    Survase, Avinash Ashok
    Sutar, Suhas Hari
    Ubale, Shivaji Bhaurao
    Kanase, Shivangi Shivraj
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2024, 953
  • [29] Defect-engineered rGO-CoNi2S4 with enhanced electrochemical performance for asymmetric supercapacitor
    Wang, Xu
    Zhao, Bo-wang
    Liang, Jia-yu
    Liu, Geng-zheng
    Guo, Ze-fei
    Hao, Hui-lian
    Li, Wen-yao
    Shen, Wen-zhong
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2025, 35 (02) : 563 - 578
  • [30] Synthesis process optimization and electrochemical properties of CoMoO4 supercapacitor prepared by in situ growth method
    Li, Ling
    Zhou, Jiyao
    Zhang, Yanwei
    Pei, Xinbin
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2022, 33 (30) : 23851 - 23866