A nested spin structure and single molecule magnet behaviour in an Fe8Dy12 heterometallic cyclic coordination cluster

被引:5
|
作者
Peng, Yan [1 ,2 ]
Braun, Jonas [1 ,3 ,4 ]
Schulze, Michael [5 ]
Kaemmerer, Hagen [1 ,4 ]
Schneider, Yannik F. [1 ,3 ]
Anson, Christopher E. [1 ]
Wernsdorfer, Wolfgang [4 ,5 ]
Powell, Annie K. [1 ,2 ,4 ]
机构
[1] Karlsruhe Inst Technol KIT, Inst Inorgan Chem, Kaiserstr 12, D-76131 Karlsruhe, Germany
[2] Jiangxi Univ Sci & Technol, Sch Chem & Chem Engn, Ganzhou 341000, Peoples R China
[3] Karlsruhe Inst Technol KIT, Inst Nanotechnol INT, Kaiserstr 12, D-76131 Karlsruhe, Germany
[4] Karlsruhe Inst Technol KIT, Inst Quantum Mat & Technol IQMT, Kaiserstr 12, D-76131 Karlsruhe, Germany
[5] Karlsruhe Inst Technol KIT, Phys Inst, Kaiserstr 12, D-76131 Karlsruhe, Germany
关键词
WHEEL; DY; LN; MAGNETIZATION; COMPLEXES; GD;
D O I
10.1039/d3dt04141g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The 20-nuclearity compound [Fe8Dy12(tea)(8)(teaH)(12)(NO3)(12)]center dot 8MeCN (where teaH(3) = triethanolamine) was synthesised and characterised through single crystal X-ray diffraction and magnetic measurements. The shape of the magnetic hysteresis in the microSQUID measurements was rationalised using the MAGELLAN program.
引用
收藏
页码:894 / 897
页数:4
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