Hydrogen Production from Gadolinium-Promoted Yttrium-Zirconium-Supported Ni Catalysts through Dry Methane Reforming

被引:10
|
作者
Fakeeha, Anis H. [1 ]
Al-Fatesh, Ahmed S. [1 ]
Srivastava, Vijay Kumar [2 ]
Ibrahim, Ahmed A. [1 ]
Abahussain, Abdulaziz A. M. [1 ]
Abu-Dahrieh, Jehad K. [3 ]
Alotibi, Mohammed F. [4 ]
Kumar, Rawesh [2 ]
机构
[1] King Saud Univ, Coll Engn, Chem Engn Dept, POB 800, Riyadh 48137, Saudi Arabia
[2] Indus Univ, Dept Chem, Ahmadabad 382115, Gujarat, India
[3] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, North Ireland
[4] King Abdulaziz City Sci & Technol KACST, Inst Refining & Petrochem Technol, POB 6086, Riyadh 83527, Saudi Arabia
来源
ACS OMEGA | 2023年 / 8卷 / 24期
关键词
CARBON DEPOSITION; GD; CO2; ZRO2; CH4; TRANSFORMATION; PERFORMANCE; CERIA; GAS;
D O I
10.1021/acsomega.3c02229
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogen production from dry reforming of methane (DRM)not onlyconcerns with green energy but also involves the consumption of twogreenhouse gases CH4 and CO2. The lattice oxygenendowing capacity, thermostability, and efficient anchoring of Nihas brought the attention of the DRM community over the yttria-zirconia-supportedNi system (Ni/Y + Zr). Herein, Gd-promoted Ni/Y + Zr is characterizedand investigated for hydrogen production through DRM. The H-2-TPR -> CO2-TPD -> H-2-TPR cyclicexperiment indicates that most of the catalytic active site (Ni) remainspresent during the DRM reaction over all catalyst systems. Upon Yaddition, the tetragonal zirconia-yttrium oxide phase stabilizes thesupport. Gadolinium promotional addition up to 4 wt % modifies thesurface by formation of the cubic zirconium gadolinium oxide phase,limits the size of NiO, and makes reducible NiO moderately interactedspecies available over the catalyst surface and resists coke deposition.The 5Ni4Gd/Y + Zr catalyst shows about similar to 80% yield of hydrogenconstantly up to 24 h at 800 degrees C.
引用
收藏
页码:22108 / 22120
页数:13
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