Thermodynamic Study of Sorption Processes of Gaseous Ferrocene on Organometallic Framework [Zn4(ndc)4(ur)2(dmf)]

被引：2
|
作者：
Zelenina, L. N. [1 ]
Chusova, T. P. [1 ]
Sapchenko, S. A. [1 ]
Gelfond, N. V. [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 02期
关键词：
porous organometallic coordination polymers; static method; phase transitions; thermodynamic characteristics; METAL-ORGANIC FRAMEWORKS;
D O I：
10.1134/S0036023622602343
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The pressure of ferrocene in the system host (organometallic framework [Zn-4(dmf)(ur)(2)(ndc)(4)])-guest (ferrocene) has been measured by static method with membrane zero-manometers in the temperature range from 324 to 462 K. As a result of the study, temperature dependences of pressure have been obtained for the transition of the guest from the host framework to the gas phase, the enthalpy and entropy of this process have been determined, and the change in the Gibbs energy during ferrocene binding by the framework has been calculated. Based on this information, conclusions have been made about the nature of interactions between host and guest molecules, and the obtained results have been compared with the previously studied benzene sorption on [Zn-4(dmf)(ur)(2)(ndc)(4)].
引用
收藏
页码：140 / 145
页数：6
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