Synthesis and crystal structure of the porous metal-organic coordination polymer [Zn4(Ndc)4(Oxdz)2] • 2H2O

被引：0
|
作者：
Aliev, S. B. [1 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 39卷 / 02期
基金：
俄罗斯基础研究基金会;
关键词：
FRAMEWORKS; HYDROGEN; STORAGE; DESIGN;
D O I：
10.1134/S1070328413020012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New metal-organic coordination polymer [Zn-4(Ndc)(4)(Oxdz)(2)] center dot 2H(2)O (H2Ndc = 2,6-naphthalenedicarboxylic acid, Oxdz = 1,3,4-oxadiazole) was prepared by heating a solution of zinc nitrate, naphthalenedicarboxylic acid, and 4-aminotriazole in DMF. Of particular interest is the in situ transformation of 4-aminotriazole into 1,3,4-oxadiazole. The structure and the composition of the obtained compounds were established by X-ray diffraction, IR spectroscopy, and elemental analysis. The metal-organic framework is electrically neutral and forms a channel structure with the pore diameter of 9 .
引用
收藏
页码：157 / 160
页数：4
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