Parametrization of the mechanically induced self-propagating high-temperature synthesis (MI-SHS) of Ti5Si3

被引：4

作者：

Juarez-Arellano, E. A. ^{[1
]}

Martinez-Garcia, A. ^{[1
]}

Winkler, B. ^{[2
]}

Perez-Lopez, T. ^{[3
]}

Padilla, J. M. ^{[4
]}

机构：

[1] Univ Papaloapan, Ctr Invest Cient, Inst Quim Aplicada, Circuito Cent 200,Parque Ind, Oaxaca 68301, Mexico

[2] Goethe Univ Frankfurt, Inst Geowissensch Kristallog Mineral, Altenhoferallee 1, D-60438 Frankfurt, Germany

[3] Univ Autonoma Campeche, Ctr Invest Corros, Ave Heroe Nacozari 480, Campeche 24079, Campeche, Mexico

[4] Univ Tecnol Ctr Veracruz, Area Tecnol,Ave Univ Carretera Fed Cuitlahuac La T, Cuitlahuac 94910, Veracruz, Mexico

来源：

CERAMICS INTERNATIONAL | 2023年 / 49卷 / 02期

关键词：

Ti5Si3; Intermetallic compounds; MI-SHS; High-energy ball-milling; Mechanochemistry; Parametrization; SHOCK-WAVE SYNTHESIS; TITANIUM SILICIDE; COMBUSTION SYNTHESIS; MICROSTRUCTURE; SI; SYSTEM; MASHS; ENERGY;

D O I：

10.1016/j.ceramint.2022.09.203

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Mechanically activated self-propagating high-temperature synthesis (MA-SHS) is one of the most used methodologies to synthesize titanium silicides, especially Ti5Si3. However, the problem in this methodology is to know the milling conditions needed to mechanically activate (MA) or mechanically induce (MI) the reaction of the starting materials. This information is fundamental for obtaining reproducible results. Therefore, the parametrization of the mechanically induced self-propagating high-temperature synthesis (MI-SHS) of Ti5Si3 is explored in the present study. A simple kinematic approach is used to parametrise the mechanically induced reaction as a function of the milling parameters, such as the angular velocity of the mill and the grinding time. The accumulated and transferred energy per hit needed to induce the MI-SHS of Ti5Si3 are predicted. A kinetic approach that allows the complete parametrization of mechanically induced reactions is also used.

引用

页码：2350 / 2358

页数：9

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