Electrochemical double layer at electrode-water interfaces: Recent advances from nonlinear spectroscopic investigations

被引：3

作者：

Xu, Pengtao ^{[1
]}

Chen, Liwei ^{[1
,2
]}

机构：

[1] Shanghai Jiao Tong Univ, In Situ Ctr Phys Sci, Shanghai Electrochem Energy Device Res Ctr SEED, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Shanghai 200240, Peoples R China

来源：

CURRENT OPINION IN ELECTROCHEMISTRY | 2023年 / 41卷

关键词：

Electrochemical double layer; Nonlinear spectroscopy; Electrode-water interface; Second-harmonic generation; Sum frequency generation; FREQUENCY-GENERATION; VIBRATIONAL SPECTROSCOPY; REACTION FIELD; CO2; REDUCTION; SUM; GRAPHENE;

D O I：

10.1016/j.coelec.2023.101373

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Exploring the electrochemical double layer (EDL) at electrodewater interfaces is of both fundamental and practical importance to electrochemical technology. Current research endeavors are dedicated to unraveling the molecular-level intricacies of the EDL. In this review, we discuss the application of nonlinear spectroscopy to address this challenging task. Specifically, we present the latest experimental progress of using second-harmonic generation and sum-frequency generation to characterize the interfacial electric fields, interfacial water structures, as well as the adsorbates and reactive species. We also discuss the challenges and opportunities of employing nonlinear spectroscopy for more in-depth characterization of electrochemical interfaces.

引用

页数：10

共 24 条

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