Translating aqueous CO2 hydrogenation activity to electrocatalytic reduction with a homogeneous cobalt catalyst

被引：4

作者：

Wang, Xinran S. ^{[1
]}

Yang, Jenny Y. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 03期

关键词：

CARBON-DIOXIDE; THERMODYNAMIC HYDRICITY; FORMATE; SOLVENT; OXIDATION;

D O I：

10.1039/d2cc05473f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular cobalt CO2 hydrogenation catalyst was explored for electrocatalytic CO2 reduction under aqueous conditions. The resulting pH-dependent selectivity between H-2 and HCO2- is rationalized with thermodynamic analysis and stoichiometric experiments.

引用

页码：338 / 341

页数：4

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