LemPhos - New P-Chiral Phospholene Core Based Ligand

被引：0
|
作者：
Wlodarczyk, Adam [1 ]
Ponikiewski, Lukasz [2 ]
机构：
[1] Marie Curie Sklodowska Univ, Inst Chem Sci, Fac Chem, Dept Organ Chem & Crystallochem, Gliniana 33, PL-20614 Lublin, Poland
[2] Gdansk Univ Technol, Fac Chem, Dept Inorgan Chem, Gabriela Narutowicza Str 11-12, PL-80233 Gdansk, Poland
来源：
SYNTHESIS-STUTTGART | 2024年 / 56卷 / 14期
关键词：
phosphines; phospholenes; ligands; nopadiene; asymmetric reactions; PHELLANPHOS; OXIDE;
D O I：
10.1055/a-2273-2826
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Synthesis and modifications of new chiral phospholene-based scaffolds are described. The construction of base molecules was accomplished via McCormack synthesis. Separation of single P-epimers was accomplished with column chromatography on silica gel.
引用
收藏
页码：2259 / 2262
页数：4
相关论文
共 50 条
  • [1] Synthesis, resolution, and reactivity of benzylmesitylphenylphosphine: A new P-chiral bulky ligand
    Albert, J
    Bosque, R
    Cadena, JM
    Delgado, S
    Granell, J
    Muller, G
    Ordinas, JI
    Bardia, MF
    Solans, X
    CHEMISTRY-A EUROPEAN JOURNAL, 2002, 8 (10) : 2279 - 2287
  • [2] Synthesis and resolution of benzylisopropylphenylphosphine a monodentate P-chiral ligand
    Albert, J
    Bosque, R
    Cadena, JM
    Granell, JR
    Muller, G
    Ordinas, JI
    TETRAHEDRON-ASYMMETRY, 2000, 11 (16) : 3335 - 3343
  • [3] New P-chiral polyfluoroalkyl phosphorodiamidite ligand in asymmetric transformations catalyzed by palladium and copper complexes
    E. B. Benetskii
    V. A. Davankov
    P. V. Petrovskii
    E. A. Rastorguev
    T. B. Grishina
    K. N. Gavrilov
    S. Rosset
    G. Bailat
    A. Alexakis
    Russian Journal of Organic Chemistry, 2008, 44 : 1846 - 1848
  • [4] New P-chiral polyfluoroalkyl phosphorodiamidite ligand in asymmetric transformations catalyzed by palladium and copper complexes
    Benetskii, E. B.
    Davankov, V. A.
    Petrovskii, P. V.
    Rastorguev, E. A.
    Grishina, T. B.
    Gavrilov, K. N.
    Rosset, S.
    Bailat, G.
    Alexakis, A.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 44 (12) : 1846 - 1848
  • [5] Synthesis and resolution of a new P-chiral hydroxy phosphine
    Albert, J
    Cadena, JM
    Delgado, S
    Granell, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 603 (02) : 235 - 239
  • [6] Synthesis of P-Chiral Dihydrobenzooxaphosphole Core for BI Ligands in Asymmetric Transformations
    Li, Guisheng
    Wang, Xiao-Jun
    Zhang, Yongda
    Tan, Zhulin
    DeCroos, Philomen
    Lorenz, Jon C.
    Wei, Xudong
    Grinberg, Nelu
    Yee, Nathan K.
    Senanayake, Chris H.
    JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (10): : 5456 - 5460
  • [7] Practical P-chiral phosphane ligand for Rh-catalyzed asymmetric hydrogenation
    Liu, DA
    Zhang, XM
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (04) : 646 - 649
  • [8] NEW P-CHIRAL PHOSPHATES, PHOSPHOROTHIOATES AND PHOSPHORO-SELENOTHIOATES
    KRZYZANOWSKA, B
    STEC, WJ
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1987, 30 (1-2): : 287 - 292
  • [9] Development of New P-Chiral P,π-Dihydrobenzooxaphosphole Hybrid Ligands for Asymmetric Catalysis
    Sieber, Joshua D.
    Chennamadhavuni, Divya
    Fandrick, Keith R.
    Qu, Bo
    Han, Zhengxu S.
    Savoie, Jolaine
    Ma, Shengli
    Samankumara, Lalith P.
    Grinberg, Nelu
    Lee, Heewon
    Song, Jinhua J.
    Senanayake, Chris H.
    ORGANIC LETTERS, 2014, 16 (20) : 5494 - 5497
  • [10] Water soluble P-chiral phosphines and racemic resolution: A new approach
    Riek, Matthew M.
    Adams, Daniel J.
    Chapp, Timothy
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
12345