Cp2ZrCl2-catalyzed synthesis of aryl substituted tertiary alcohols by the reaction of aryl olefins with ketones under the action of AlCl3 and Mg

被引:1
|
作者
Dil'mukhametova, Liaisan K. [1 ]
Shaibakova, Mariya G. [1 ]
Ramazanov, Ilfir R. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prospekt Oktyabrya, Ufa 450075, Russia
基金
俄罗斯科学基金会;
关键词
Aluminum chloride; Aryl substituted olefins; Ketones; Tertiary alcohols; Catalysis; Zirconocene; CATALYTIC ENANTIOSELECTIVE ALLYLATION; C BOND FORMATION; ASYMMETRIC ADDITION; ELECTROORGANIC CHEMISTRY; COUPLING REACTIONS; GRIGNARD-REAGENTS; CYCLIZATION; TRANSFORMATIONS; CYCLOPENTANOLS; METALLACYCLES;
D O I
10.1016/j.jorganchem.2023.122978
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An efficient one-step method for the synthesis of aryl substituted tertiary alcohols based on the reaction of aryl olefins with ketones under the action of AlCl3 and Mg in the presence of catalytic amounts of Cp2ZrCl2 was developed
引用
收藏
页数:8
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