Choline chloride aqueous solution: A thermophysical study

被引:4
|
作者
Gaioto, Renata Cazelato [1 ]
Dias, Mariana Carolina Gipiela Correa [1 ]
Ndiaye, Papa Matar [2 ]
Igarashi-Mafra, Luciana [1 ]
Mafra, Marcos R. [1 ]
机构
[1] Fed Univ Parana UFPR, Polytech Ctr, Dept Chem Engn, Grad Program Food Engn, BR-81531990 Curitiba, PR, Brazil
[2] Fed Univ Rio de Janeiro UFRJ, Alberto Luiz Coimbra Inst Grad Studies & Res Engn, Technol Ctr, Chem Engn Dept, BR-21941972 Rio De Janeiro, RJ, Brazil
关键词
Solubility; Density; Dynamic viscosity; Sound velocity; Molecular interaction; DEEP EUTECTIC SOLVENTS; APPARENT MOLAR VOLUME; PLUS METHYL ACETATE; ISENTROPIC COMPRESSIBILITY; DIETARY CHOLINE; IONIC LIQUID; 1-BUTYL-3-METHYLIMIDAZOLIUM BROMIDE; REFRACTIVE-INDEX; SURFACE-TENSION; WATER;
D O I
10.1016/j.fluid.2023.113903
中图分类号
O414.1 [热力学];
学科分类号
摘要
Choline Chloride (ChCl) is a salt considered necessary in several areas since health until technology. In this work, experimental data were analyzed by solubility (293.15 to 343.15 K), density (278.15 to 353.15 K), speed of sound (278.15 to 353.15 K), and dynamic viscosity (293.15 to 353.15 K) to choline chloride aqueous solutions with different solute molalities at atmospheric pressure. Thermodynamic properties such as Gibbs energy and entropy, apparent molar volume, isentropic and apparent molar compressibility, and Arrhenius activation energy of the viscous flow were evaluated from these data. These data allow a qualitative understanding of the solution behavior through solute-solvent and solute-solute interactions. In addition, surface tension data at 298.15 K in different concentrations was determined to identify what kind of behavior has this organic compound. Molar volume and isentropic compressibility data suggest significant ionic interactions and changes in the ion hy-dration with increasing concentration. In addition, the system presents a clathrate-like formation in the structure. Furthermore, the interfacial behavior classifies the salt as a surfactant.
引用
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页数:13
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