Synthesis of an iron-based metal-organic framework with octahedral cages for the selective capture of sulfur hexafluoride

被引：0

作者：

Wang, Hao ^{[1
,2
,3
]}

Shi, Le ^{[2
,3
]}

Cao, Honghao ^{[2
,3
]}

Xiong, Zhangyi ^{[2
,3
]}

Ma, Si ^{[2
,3
]}

Pan, Jun ^{[1
]}

Chen, Zhijie ^{[2
,3
]}

机构：

[1] Zhejiang Univ Technol, Coll Mat Sci & Engn, Hangzhou 310014, Peoples R China

[2] Zhejiang Univ, Stoddart Inst Mol Sci, Dept Chem, State Key Lab Silicon & Adv Semicond Mat, Hangzhou 310058, Peoples R China

[3] Zhejiang Univ, ZJU Hangzhou Global Sci & Technol Innovat Ctr, Zhejiang Israel Joint Lab Selfassembling Funct Ma, Hangzhou 311215, Peoples R China

来源：

CRYSTENGCOMM | 2024年 / 26卷 / 13期

基金：

中国国家自然科学基金;

关键词：

SF6; SEPARATION; ADSORPTION; MOF; MEMBRANES; CLUSTERS;

D O I：

10.1039/d4ce00041b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The assembly of a metal-organic framework (MOF) containing bent phenanthroline linkers and iron trinuclear clusters remains rare. Herein, we report the synthesis and single crystal structure of a two-dimensional (2D) MOF, Fe-cage-MOF, assembled from 2,9-substituted phenanthroline based carboxylate linkers and pre-synthesized iron trinuclear clusters. The distinctive octahedral cages and ordered 1D channels endow the MOF with permanent porosity and potential for selective capture of the greenhouse gas sulfur hexafluoride. An iron-based metal-organic framework with octahedral cages for the effective capture of sulfur hexafluoride.

引用

页码：1912 / 1916

页数：5

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