(S)-N1,N3-Dibenzyl-1-cyclohexyl-N1,N3-bis((R)-1-phenylethyl)propane-1,3-diamine

被引：0

作者：

Belda, Leland ^{[1
]}

Garcia-Gonzalez, Angel ^{[1
]}

Manchado, Alejandro ^{[1
]}

Nieto, Carlos T. T. ^{[1
]}

Garrido, Narciso M. M. ^{[1
]}

机构：

[1] Univ Salamanca, Fac Chem Sci, Dept Organ Chem, Pl Caidos S-N, Salamanca 37008, Spain

来源：

MOLBANK | 2023年 / 2023卷 / 01期

关键词：

1; 3-diamine; chiral auxiliar; chiral lithium amide; organocatalysis; aza-Michael addition; PURE LITHIUM AMIDES; ASYMMETRIC-SYNTHESIS; AMMONIA EQUIVALENTS; CONJUGATE ADDITION; DERIVATIVES; ACID; 1,3-DIAMINES; SPARTEINE; LIGANDS;

D O I：

10.3390/M1544

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(S)-N-1,N-3-dibenzyl-1-cyclohexyl-N-1,N-3-bis((R)-1-phenylethyl)propane-1,3-diamine was prepared in good yield by the reduction of the corresponding amide, which was obtained by the addition of a chiral lithium amide to an alpha,beta-unsaturated ester. The target compound was fully characterized by NMR (H-1 and C-13), high-resolution mass spectrometry and polarimetry.

引用

页数：5

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