Flexible cobalt nanoparticles/carbon nanofibers with macroporous structures toward superior electromagnetic wave absorption

The increasing electromagnetic (EM) pollution that has seriously threatened human health and electronic devices urgently required high-performance absorbents toward attenuating EM wave (EMW). The com-bination of microstructure modulation and appropriate components regulation has proven to be a feasi-ble strategy for improving the EMW absorption performance of absorbents. In this work, well-designed one-dimensional carbon nanofibers with macroporous structures and uniformly magnetic metal nanoparticles modification were prepared by the hard-template assisted electrospinning method fol-lowed by carbonization and template-elimination processes. The strong interfacial polarization loss and multireflection strengthened by the hollow structures and the magnetic loss induced by the intro-duced cobalt nanoparticles evidently enhanced the impedance matching level of the macroporous carbon nanofibers/cobalt nanoparticles (MCF/Co). As a result, MCF/Co composite offers broad absorption band-width (6.24 GHz) and strong electromagnetic wave absorption performance (-40.1 dB) at a thickness of 3.0 mm. This work inspires the rational one-dimensional macroporous carbon nanofibers design for new-generation EMW materials and provides an important research basis for the porous flexible EMW absorption materials.(c) 2023 Elsevier Inc. All rights reserved.