Mechanism of the Decrease in Surface Tension by Bulk Nanobubbles (Ultrafine Bubbles)

The mechanism of the decrease in the surface tension of water containing bulk nanobubbles (ultrafine bubbles) is studied theoretically by numerical simulations of the adsorption of bulk nanobubbles at the liquid's surface based on the dynamic equilibrium model for the stability of a bulk nanobubble under the conditions of the Tuziuti experiment (Tuziuti, T., et al., Langmuir, 2023, 39, 5771-5778). It is predicted that the concentration of bulk nanobubbles in the bulk liquid decreases considerably with time, as many bulk nanobubbles are gradually adsorbed at the liquid's surface. A part of the decrease in surface tension is due to the Janus-like structure of a bulk nanobubble that could partly break the hydrogen bond network of water molecules at the liquid's surface because more than 50% of the bubble's surface is covered with hydrophobic impurities, according to the dynamic equilibrium model. The theoretically estimated decrease in surface tension due to the Janus-like structure of a bulk nanobubble agrees with the experimental data of the decrease in surface tension solely by bulk nanobubbles obtained by the comparison of before and after the elimination of bulk nanobubbles by the freeze-thaw process. This effect cannot be explained by the electric charge stabilization model widely discussed for the stability of a bulk nanobubble, although the present model is only applicable to the solution containing hydrophobic impurities. Another part of the decrease in surface tension should be due to impurities produced from a nanobubble generator, such as a mechanical seal, which was partly confirmed by the TOC measurements.