Spin-induced electron transmission through metal-organic chiral crystals

被引:7
|
作者
Das, Tapan Kumar [1 ]
Mondal, Amit Kumar [1 ,5 ]
Tiwari, Om Shanker [2 ]
Makam, Pandeeswar [2 ]
Leitus, Gregory [3 ]
Gazit, Ehud [2 ]
Claudio, Fontanesi [4 ]
Naaman, Ron [1 ]
机构
[1] Weizmann Inst Sci, Dept Chem & Biol Phys, IL-7610001 Rehovot, Israel
[2] Tel Aviv Univ, George S Wise Fac Life Sci, Shmunis Sch Biomed & Canc Res, IL-6997801 Tel Aviv, Israel
[3] Weizmann Inst Sci, Chem Res Support, IL-7610001 Rehovot, Israel
[4] Univ Modena & Reggio Emilia, Dept Engn Enzo Ferrari, I-41125 Modena, Italy
[5] Inst Nano Sci & Technol INST, Sect 81, Mohali 140306, Punjab, India
关键词
SINGLE-CRYSTALS; FRAMEWORKS; TRANSPORT;
D O I
10.1039/d3cp02579a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal-organic Co(ii)-phenylalanine crystals were studied and were found to possess magnetic properties and long-range spin transport. Magnetic measurements confirmed that in the crystals there are antiferromagnetic interactions between Co(ii) and the lattice. The metal-organic crystals (MOCs) also present the chirality-induced spin selectivity (CISS) effect at room temperature. A long-range spin polarization is observed using a magnetic conductive-probe atomic force microscope. The spin polarization is found to be in the range of 35-45%.
引用
收藏
页码:22124 / 22129
页数:6
相关论文
共 50 条
  • [31] Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis
    Jiang, Xian-Fa
    Shao, Chongyun
    Ouyang, Zhongwen
    Hu, Zhao-Bo
    Wang, Zhenxing
    Song, You
    CHINESE CHEMICAL LETTERS, 2024, 35 (07)
  • [32] Generating electron spin qubit in metal-organic frameworks via spontaneous hydrolysis
    XianFa Jiang
    Chongyun Shao
    Zhongwen Ouyang
    ZhaoBo Hu
    Zhenxing Wang
    You Song
    ChineseChemicalLetters, 2024, 35 (07) : 555 - 559
  • [33] Combining electron transfer, spin crossover, and redox properties in metal-organic frameworks
    Getzner, Livia
    Paliwoda, Damian
    Vendier, Laure
    Lawson-Daku, Latevi Max
    Rotaru, Aurelian
    Molnar, Gabor
    Cobo, Saioa
    Bousseksou, Azzedine
    NATURE COMMUNICATIONS, 2024, 15 (01)
  • [34] Chiral environment of catalytic sites in the chiral metal-organic frameworks
    Lee, Misun
    Shin, Sung Min
    Jeong, Nakcheol
    Thallapally, Praveen K.
    DALTON TRANSACTIONS, 2015, 44 (20) : 9349 - 9352
  • [35] Synthetic strategies for chiral metal-organic frameworks
    Zongsu Han
    Wei Shi
    Peng Cheng
    Chinese Chemical Letters, 2018, 29 (06) : 819 - 822
  • [36] A new chiral metal-organic framework with spiranes
    Kovats, E.
    Foldes, D.
    Bortel, G.
    Pekker, S.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2024, 80
  • [37] In situ transmission electron microscopy to monitor phase transitions in metal-organic frameworks
    Jianhui Zhang
    Wenhua Zhao
    Jun Wang
    Meiyun Lai
    Xuexue Pan
    Journal of Nanoparticle Research, 2023, 25
  • [38] Synthetic strategies for chiral metal-organic frameworks
    Han, Zongsu
    Shi, Wei
    Cheng, Peng
    CHINESE CHEMICAL LETTERS, 2018, 29 (06) : 819 - 822
  • [39] New mesoporous chiral metal-organic frameworks
    Kaskel, Stefan
    Senkovska, Irena
    Klein, Nicole
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [40] In situ transmission electron microscopy to monitor phase transitions in metal-organic frameworks
    Zhang, Jianhui
    Zhao, Wenhua
    Wang, Jun
    Lai, Meiyun
    Pan, Xuexue
    JOURNAL OF NANOPARTICLE RESEARCH, 2023, 25 (06)