Densities, Viscosities and Refractive Indices for Binary Mixtures of Diethyl Carbonate with Fatty Acid Ethyl Esters

被引:0
|
作者
Li, Dan [1 ]
Zheng, Yingdi [1 ]
Jin, Yang [1 ]
Li, Yixin [1 ]
机构
[1] Weifang Univ, Dept Chem & Chem Engn, Weifang 261061, Shandong, Peoples R China
关键词
Diethyl carbonate; Excess molar volume; Viscosity; Refractive index; EXCESS MOLAR VOLUMES; DIMETHYL CARBONATE; COLD FLOW; PALM-OIL; BIODIESEL PRODUCTION; DIALKYL CARBONATES; SURFACE TENSIONS; METHYL; SPEED; SOUND;
D O I
10.1007/s10953-023-01295-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fundamental physical properties including density, viscosity and refractive index have been measured for binary mixtures of four fatty acid ethyl esters mixed with diethyl carbonate (DEC) over the entire composition range at temperatures T = (293.15 to 323.15) K and normal atmospheric pressure. The values of excess molar volume, viscosity deviation and refractive index deviation are calculated and the effects of temperature and composition on the variation of excess properties are discussed. All of the values of excess molar volume and refractive index deviation are observed to be positive and the values of viscosity deviation are negative. The excess or deviation properties have also been evaluated and fitted to the Redlich-Kister equation with satisfied results.
引用
收藏
页码:1048 / 1065
页数:18
相关论文
共 50 条
  • [21] Densities, excess molar volumes, and refractive indices of ethyl acetate and aromatic hydrocarbon binary mixtures
    Resa, JM
    González, C
    de Landaluce, O
    Lanz, J
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2002, 34 (07): : 995 - 1004
  • [22] Densities, Viscosities, Sound Speeds, Refractive Indices, and Excess Properties of Binary Mixtures of Isoamyl Alcohol with Some Alkoxyethanols
    Mahendra Nath Roy
    Radhey Shyam Sah
    Prasanna Pradhan
    International Journal of Thermophysics, 2010, 31 : 316 - 326
  • [23] Densities, viscosities, and refractive indices of binary liquid mixtures of hexane, decane, hexadecane, and squalane with benzene at 298.15 K
    Lal, K
    Tripathi, N
    Dubey, GP
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (05): : 961 - 964
  • [24] Densities, viscosities, and refractive indices for binary and ternary mixtures of acetone, ethanol, and 2,2,4-trimethylpentane
    Chen, HW
    Tu, CH
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (04): : 1262 - 1269
  • [25] Densities, Viscosities, Sound Speeds, Refractive Indices, and Excess Properties of Binary Mixtures of Isoamyl Alcohol with Some Alkoxyethanols
    Roy, Mahendra Nath
    Sah, Radhey Shyam
    Pradhan, Prasanna
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2010, 31 (02) : 316 - 326
  • [26] Densities, speeds of sound, isentropic compressibilities, refractive indices and viscosities of binary mixtures of tetrahydrofuran with hydrocarbons at 303.15 K
    Oswal, SL
    Gardas, RL
    Phalak, RP
    JOURNAL OF MOLECULAR LIQUIDS, 2005, 116 (02) : 109 - 118
  • [27] Densities, viscosities and refractive indices of binary liquid mixtures of methyl tert-butyl ether or ethyl tert-butyl ether with a hydrocarbon fuel
    Li, Dan
    Qin, Xiaomei
    Fang, Wenjun
    Guo, Meng
    Wang, Huiqin
    Feng, Yimin
    EXPERIMENTAL THERMAL AND FLUID SCIENCE, 2013, 48 : 163 - 168
  • [28] Binary mixtures of fatty acid ethyl esters: Solid-liquid equilibrium
    Boros, Laslo A. D.
    Batista, Marta L. S.
    Coutinho, J. A. P.
    Krahenbuhl, M. A.
    Meirelles, Antonio J. A.
    Costa, Mariana C.
    FLUID PHASE EQUILIBRIA, 2016, 427 : 1 - 8
  • [29] Densities, viscosities, and refractive indices of binary mixtures of anisole with benzene, methylbenzene, ethylbenzene, propylbenzene, and butylbenzene at (293.15 and 303.15) K
    Al-Kandary, JA
    Al-Jimaz, AS
    Abdul-Latif, AHM
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (01): : 99 - 103
  • [30] Enzymatic synthesis of fatty acid ethyl esters by utilizing camellia oil soapstocks and diethyl carbonate
    Wang, Yingying
    Cao, Xuejun
    BIORESOURCE TECHNOLOGY, 2011, 102 (22) : 10173 - 10179