Densities, Viscosities and Refractive Indices for Binary Mixtures of Diethyl Carbonate with Fatty Acid Ethyl Esters

被引:0
|
作者
Li, Dan [1 ]
Zheng, Yingdi [1 ]
Jin, Yang [1 ]
Li, Yixin [1 ]
机构
[1] Weifang Univ, Dept Chem & Chem Engn, Weifang 261061, Shandong, Peoples R China
关键词
Diethyl carbonate; Excess molar volume; Viscosity; Refractive index; EXCESS MOLAR VOLUMES; DIMETHYL CARBONATE; COLD FLOW; PALM-OIL; BIODIESEL PRODUCTION; DIALKYL CARBONATES; SURFACE TENSIONS; METHYL; SPEED; SOUND;
D O I
10.1007/s10953-023-01295-y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The fundamental physical properties including density, viscosity and refractive index have been measured for binary mixtures of four fatty acid ethyl esters mixed with diethyl carbonate (DEC) over the entire composition range at temperatures T = (293.15 to 323.15) K and normal atmospheric pressure. The values of excess molar volume, viscosity deviation and refractive index deviation are calculated and the effects of temperature and composition on the variation of excess properties are discussed. All of the values of excess molar volume and refractive index deviation are observed to be positive and the values of viscosity deviation are negative. The excess or deviation properties have also been evaluated and fitted to the Redlich-Kister equation with satisfied results.
引用
收藏
页码:1048 / 1065
页数:18
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