Rotational isomerization: spontaneous structural transformation of a thermally activated delayed fluorescence binuclear copper(i) complex

被引：4
|
作者：
Zhang, Xiao-Wen [1 ,2 ,3 ]
Huang, Chun-Hua [1 ,2 ,4 ]
Yang, Mingxue [1 ,2 ]
Chen, Xu-Lin [1 ,2 ]
Lu, Can-Zhong [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
[3] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
[4] Sun Yat Sen Univ, Affiliated Hosp 8, Shenzhen 518033, Peoples R China
来源：
DALTON TRANSACTIONS | 2023年 / 52卷 / 29期
基金：
中国国家自然科学基金;
关键词：
Coordination reactions - Copper compounds - Fluorescence - Isomerization;
D O I：
10.1039/d3dt01258a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel binuclear Cu(i) halide complex, Cu2I2(DPPCz)(2), which emits efficient thermally activated delayed fluorescence (TADF), is reported. The crystal of this complex spontaneously undergoes ligand rotation and coordination-configuration transformation, converting to its isomer without any external stimulation.
引用
收藏
页码：9893 / 9898
页数：6
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