Cobalt(<sc>ii</sc>)-catalyzed peri-C(sp2)-H selective hydroxylation of naphthalene monoimides

被引：0
|
作者：
Chand, Tapasi [1 ]
Gupta, Princi [1 ]
Oza, Nehali [1 ]
Kapur, Manmohan [1 ]
机构：
[1] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Bhopal Bypass Rd, Bhopal 462066, MP, India
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 13期
关键词：
FLUORESCENT-PROBE; OXIDATION; WATER;
D O I：
10.1039/d3cc06050k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reported herein is an efficient and eco-friendly peri-selective monohydroxylation of naphthalene monoimides (NMIs) to access 4-hydroxy NMIs, which possess multidisciplinary applications. The key aspect of this method is the utilization of cobalt(II)-catalysis via a single electron transfer mechanism to achieve site-selective C(sp(2))-hydroxylation. Transformation of the hydroxyl group into pseudohalides reveals its applications towards cross-coupling reactions.
引用
收藏
页码：1770 / 1773
页数：4
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