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SrTiO3-modified Bi0.5Na0.47Li0.03Ti0.99Sn0.01O3 relaxor ferroelectric ceramics with high energy storage performance
被引:6
|作者:
Lu, Ying
[1
]
Li, Peng
[1
]
Du, Juan
[1
]
Hu, Chengchao
[1
]
Hao, Jigong
[1
,4
]
Zhao, Kunyu
[2
,3
]
Zeng, Huarong
[2
,3
,5
]
Li, Wei
[1
,4
]
机构:
[1] Liaocheng Univ, Coll Mat Sci & Engn, Liaocheng, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai, Peoples R China
[3] Univ Chinese Acad Sci, Mat & Optoelect Res Ctr, Beijing, Peoples R China
[4] Liaocheng Univ, Coll Mat Sci & Engn, Liaocheng 252059, Peoples R China
[5] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 200050, Peoples R China
基金:
中国国家自然科学基金;
关键词:
BNT-based ceramics;
energy storage;
phase structure;
temperature stability;
LOW ELECTRIC-FIELDS;
THERMAL-STABILITY;
DENSITY;
EFFICIENCY;
TEMPERATURE;
OPTIMIZATION;
COMPOSITES;
D O I:
10.1111/ijac.14360
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
(1 - x)Bi0.5Na0.47Li0.03Ti0.99Sn0.01O3-xSrTiO(3) (BNLST-xST) lead-free ceramics were synthesized by traditional solid phase sintering. When x = 0.4, the ceramic achieves a high energy storage density W-rec of 3.78 J/cm(3) as well as a superior efficiency eta of 90.3% under 360 kV/cm. The charge-discharge curves related to temperature and cycle show that the 0.6BNLST-0.4ST sample has good temperature stability (20-180 degrees C) and cycling reliability (variation of W-D < 5%). Moreover, a fast discharge rate (t(0.9) = 0.219 mu s) and a large discharge energy density (W-D = 1.89 J/cm(3)) are achieved at 220 kV/cm. The results show that BNLST-xST energy storage ceramics are promising materials for devices with pulsed power capacitor.
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页码:2350 / 2359
页数:10
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