Sulfur chemistry in action. New perspectives for organic synthesis

被引：1
|
作者：
Zard, Samir Z. [1 ,2 ]
机构：
[1] Ecole Polytech, Lab Synth Organ Associe, UMR 7652, CNRS, Palaiseau, France
[2] Ecole Polytech, Lab Synth Organ Associe, UMR 7652, CNRS, F-91128 Palaiseau, France
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2023年 / 198卷 / 06期
关键词：
Alkene isomerization; radial addition; xanthates; ketones; boronates; S-ALKYL-THIONOCARBONATES; RADICAL STABILIZATION ENERGIES; BARTON-MCCOMBIE DEOXYGENATION; VINYLOGOUS ALDOL; REDUCTION; XANTHATES; BOND; ROUTE; REARRANGEMENT; SUBSTITUENTS;
D O I：
10.1080/10426507.2023.2173755
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The radical chemistry based on organosulfur derivatives constitutes a powerful tool for solving synthetic problems. The present short overview discusses a method for the contra-thermodynamic isomerization of trisubstituted cycloalkenes into the less stable disubstituted regioisomer. It also describes the use of xanthates as radical precursors for the synthesis and modification of ketones and for accessing a wide range of boronates.
引用
收藏
页码：456 / 465
页数：10
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