Catalytic properties of metals of the 2nd and 12th groups in cumene oxidation

被引：0

作者：

Ulitin, Nikolai V. ^{[1
]}

Tereshchenko, Konstantin A. ^{[1
]}

Novikov, Nikolay A. ^{[1
]}

Shiyan, Daria A. ^{[1
]}

Lyulinskaya, Yana L. ^{[1
]}

Nurullina, Natalia M. ^{[1
]}

Denisova, Marina N. ^{[1
]}

Anisimova, Viktoriya I. ^{[1
]}

Nurmurodov, Talat Sh. ^{[1
]}

Kharlampidi, Kharlampii E. ^{[1
]}

机构：

[1] Kazan Natl Res Technol Univ, Kazan 420015, Russia

来源：

APPLIED CATALYSIS A-GENERAL | 2023年 / 653卷

基金：

俄罗斯科学基金会;

关键词：

Catalytic cumene oxidation; Cumene; Cumene hydroperoxide; Kinetic modeling; LIQUID-PHASE OXIDATION; AEROBIC OXIDATION; CARBON NANOTUBES; HYDROPEROXIDE; KINETICS; OXIDE; PHOTOOXIDATION; HYDROCARBONS; AUTOXIDATION; REACTIVITY;

D O I：

10.1016/j.apcata.2023.119044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Using kinetic modeling, a comparative study of the catalytic properties of metals of the 2nd and 12th groups (Mg, Ca, Sr, Ba, Zn, Cd, Hg) in the composition of 2-ethylhexanoates was carried out in the industrial cumene oxidation. It has been established that: 1) in terms of the combination of catalytic properties (acceleration of cumene oxidation and selectivity), it is necessary to recognize Mg and Cd to be the best: Mg accelerates the process more strongly than Cd, but Cd lowers the selectivity to a lesser extent relative to the selectivity of the non-catalytic process (the selectivity at a low initial catalyst concentration is comparable to the selectivity of a non-catalytic process); 2) the values of the accumulation rate of cumene hydroperoxide (target product) in the industrial cumene oxidation correlate with the values of the covalent atomic radii of the corresponding metals.

引用

页数：13

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