Cobalt(iii)-catalyzed synthesis of isoquinolines from oximes and alkynes in deep eutectic solvents

被引：5
|
作者：
Wang, Liang [1 ]
Zhang, Lingfeng [1 ]
Gong, Ling [1 ]
机构：
[1] Changzhou Vocat Inst Engn, Sch Chem & Pharmaceut Engn, Changzhou 213164, Peoples R China
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 02期
关键词：
C-H activation; annulation; oximes; alkynes; cobalt catalysis; isoquinolines; BIOMASS-DERIVED SOLVENTS; C-H; BOND ACTIVATION; O BOND; ANNULATION;
D O I：
10.1016/j.mencom.2023.02.030
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A cobalt-catalyzed redox-neutral [4 + 2] annulation of oximes and alkynes in deep eutectic solvents comprising quaternary ammonium compounds and hydrogen bond donors has been developed, the best system being Me3N+CH2CO2-/HOCH(CF3)2. No external oxidizing reagent was required, and only water was generated as the secondary product. The catalytic system can be reused in three consecutive cycles.
引用
收藏
页码：243 / 245
页数：3
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