Insights of pristine stainless steel mesh oxygen evolution reaction in diverse concentrations of potassium hydroxide

被引:6
|
作者
Karthik, Namachivayam [1 ]
Atchudan, Raji [2 ]
Edison, Thomas Nesakumar Jebakumar Immanuel [3 ]
Choi, Seung Tae [1 ]
机构
[1] Chung Ang Univ, Sch Mech Engn, Funct Mat & Appl Mech Lab, Seoul 06974, South Korea
[2] Yeungnam Univ, Sch Chem Engn, Gyeongbuk 38541, South Korea
[3] Sethu Inst Technol, Dept Chem, Virudunagar 626115, Tamil Nadu, India
基金
新加坡国家研究基金会;
关键词
Stainless-steel mesh; Potassium hydroxide concentration; Oxygen evolution reaction; Specific conductivity; (hydro)oxides; ELECTROCATALYST;
D O I
10.1016/j.matlet.2022.133557
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Stainless steel, a cost-effective Fe, Ni, and Cr alloy, is a promising electrode material for green electrochemical energy conversion systems. Accordingly, this study investigated the effect of potassium hydroxide concentration (KOH; 0.1, 1.0, and 6.0 M) on the oxygen evolution reaction (OER) activity of pristine stainless-steel mesh (pre-SSM) used for the different concentrations denoted by SSM-0.1, SSM-1.0, and SSM-6.0). In particular, SSM-6.0 showed satisfactory OER activity with a low overpotential of 223 mV, and a Tafel slope of 44 mV dec-1 was required to achieve a current density of 10 mA cm-2. This remarkable performance of the electrode resulted from the 6.0 M KOH solution having a considerably higher theoretical specific conductivity (0.6266 S cm -1) than the 1.0 M (0.2153 S cm-1) and 0.1 M (0.0241 S cm-1) KOH solutions.
引用
收藏
页数:4
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