Cp2Fe-Mediated Electrochemical Synthesis of Phosphorylated Oxindoles and Indolo[2,1-a]isoquinolin-6(5H)-ones

被引：6
|
作者：
Zhou, Xiaocong [1 ]
Wang, Jian [1 ]
Shen, Yirui [2 ,3 ]
Ma, Dumei [4 ]
Zhao, Yufen [1 ]
Wu, Ju [1 ]
机构：
[1] Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China
[2] Ningbo Univ Technol, Sch Mat & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
[3] Tianjin Univ, Zhejiang Inst, Ningbo 315201, Zhejiang, Peoples R China
[4] Ningbo Univ, Inst Mass Spectrometry, Sch Mat Sci & Chem Engn, Key Lab Adv Mass Spectrometry & Mol Anal Zhejiang, Ningbo 315211, Zhejiang, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 24期
基金：
中国国家自然科学基金;
关键词：
N-ARYLACRYLAMIDES; ACTIVATED ALKENES; FUNCTIONALIZATION; CASCADE; ARYLSULFONYLATION; CARBOAZIDATION; ACRYLAMIDES;
D O I：
10.1021/acs.joc.3c02017
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and environmentally friendly electrochemical synthesis of phosphorylated oxindoles and indolo-[2,1-a]-isoquinolin-6-(5H)-ones mediated by readily available Cp2Fe has been developed, which illustrated a broad substrate scope and diverse functional group compatibility. This protocol featured an external oxidant-free process and was at room temperature, which was proposed to be driven by the anodic oxidation of Cp2Fe.
引用
收藏
页码：17521 / 17526
页数：6
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