Halogen bonding in chloroiodates(<sc>iii</sc>)

被引：0

作者：

Korobeynikov, Nikita A. ^{[1
]}

Usoltsev, Andrey N. ^{[1
]}

Sokolov, Maxim N. ^{[1
]}

Novikov, Alexander S. ^{[2
,3
]}

Sukhikh, Taisiya S. ^{[1
]}

Adonin, Sergey A. ^{[1
,4
]}

机构：

[1] RAS, SB, Nikolaev Inst Inorgan Chem, Lavrentieva St 3, Novosibirsk 630090, Russia

[2] St Petersburg State Univ, Inst Chem, Univ Sky St 26, St Petersburg 198504, Russia

[3] RUDN Univ, Peoples Friendship Univ Russia, Res Inst Chem, Miklukho Maklaya St 6, Moscow 117198, Russia

[4] RAS, Irkutsk Favorsky Inst Chem, SB, Favorsky St 1, Irkutsk 664033, Russia

来源：

CRYSTENGCOMM | 2023年 / 25卷 / 37期

基金：

俄罗斯科学基金会;

关键词：

SIGMA-HOLE DONOR; SYNTHETIC APPLICATIONS; DIARYLIODONIUM; TETRACHLOROIODATE(III); CRYSTALS; IONS;

D O I：

10.1039/d3ce00400g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of iodides of organic cations by dichlorine in aqueous HCl results in salts of tetrachloroiodate(iii) [ICl4](-). Within this series of compounds, the formation of halogen bonding between the iodine and chlorine atoms is common, leading to the assembly of supramolecular associations in the solid state. The nature of these interactions was examined by theoretical methods.

引用

页码：5233 / 5237

页数：5

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