Microwave synthesized N-doped carbon dots for dual mode detection of Hg (II) ion and degradation of malachite green dye

被引:8
|
作者
Thara, Chinnu R. [1 ]
Mathew, Beena [1 ]
机构
[1] Mahatma Gandhi Univ, Sch Chem Sci, Kottayam 686560, Kerala, India
关键词
Microwave synthesis; Carbon dots; Mercuric ion; Fluorescent sensing; Electrochemical sensing; Malachite degradation; Catalytic degradation; FLUORESCENCE; NITROGEN; PROBE;
D O I
10.1016/j.talanta.2023.125278
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
One of the most intriguing materials today is carbon dots, which offer a variety of possible uses owing to their distinct photophysical and chemical characteristics. The current study examines the electrochemical and photochemical aspects of carbon dots produced in a single pot for environmental sustainability. Domestic microwave-assisted pyrolysis of urea and glucose yielded chemically synthesized nitrogen-doped carbon dots (microwave synthesized N-doped carbon dots (M-NCDs)) with blue fluorescence and a quantum yield of 14.9 %. High water dispersibility, stability, and biocompatibility were the significant attributes of synthesized M-NCDs. Customarily fluorescent carbon dots were initially used for sensing studies. Fluorescent and electrochemical studies manifest the excellent stability, sensitivity, and selectivity of M-NCDs for mercuric ions. Both methods' Hg (II) procure detection limits of 3.5 nM and 6.1 nM. In addition to sensing traits, the subsequent section deals with the potential of M-NDCs to bring about the exhaustive degradation of malachite green (MG) dye. Within 60 min, 98 % of the dye was catalytically degraded by M-NCD by first-order kinetics based on the LangmuirHinshelwood model. This is the first time reporting the catalytic degradation of malachite green dye utilizing carbon dot in its natural form rather than being doped with any metal atom or converted to any composite form.
引用
收藏
页数:8
相关论文
共 50 条
  • [31] Detection of Dopamine in Human Fluids Using N-Doped Carbon Dots
    Louleb, Marwa
    Latrous, Latifa
    Rios, Angel
    Zougagh, Mohammed
    Rodriguez-Castellon, Enrique
    Algarra, Manuel
    Soto, Juan
    ACS APPLIED NANO MATERIALS, 2020, 3 (08) : 8004 - 8011
  • [32] Carbon dots as a fluorescent ink and dual-mode probe for the efficient detection of doxycycline and Hg(II) ions
    Binila K. Korah
    Neenamol John
    Bony K. John
    Sneha Mathew
    D. Bijimol
    Beena Mathew
    Journal of Materials Research, 2022, 37 : 3060 - 3070
  • [33] Carbon dots as a fluorescent ink and dual-mode probe for the efficient detection of doxycycline and Hg(II) ions
    Korah, Binila K.
    John, Neenamol
    John, Bony K.
    Mathew, Sneha
    Bijimol, D.
    Mathew, Beena
    JOURNAL OF MATERIALS RESEARCH, 2022, 37 (18) : 3060 - 3070
  • [34] A fluorescent probe based on N-doped carbon dots for highly sensitive detection of Hg2+ in aqueous solutions
    Gao, Zhi-hao
    Lin, Zheng-zhong
    Chen, Xiao-mei
    Zhong, Hui-ping
    Huang, Zhi-yong
    ANALYTICAL METHODS, 2016, 8 (10) : 2297 - 2304
  • [35] N-doped, silver, and cerium co-doped carbon quantum dots based sensor for detection of Hg2+ and captopril
    Dewangan, Lakshita
    Chawre, Yogyata
    Korram, Jyoti
    Karbhal, Indrapal
    Nagwanshi, Rekha
    Jain, Vishal
    Satnami, Manmohan L.
    MICROCHEMICAL JOURNAL, 2022, 182
  • [36] Microwave-assisted rapid preparation of N-doped carbon dots for ultra-sensitive detection of copper
    Gao, Xu
    Qin, Jing
    Liu, Xu
    Hou, Juan
    Chinese Journal of Analysis Laboratory, 2022, 41 (04) : 413 - 418
  • [37] Microwave Synthesis of Blue Emissive N-Doped Carbon Quantum Dots as a Fluorescent Probe for Free Chlorine Detection
    Larsson, Melissa Asha
    Ramachandran, Pravena
    Jarujamrus, Purim
    Lee, Hooi Ling
    SAINS MALAYSIANA, 2022, 51 (04): : 1197 - 1212
  • [38] Green and facile microwave assisted synthesis of (metal-free) N-doped carbon quantum dots for catalytic applications
    Prekodravac, Jovana
    Vasiljevic, Bojana
    Markovic, Zoran
    Jovanovic, Dragana
    Kleut, Duska
    Spitalsky, Zdenko
    Micusik, Matej
    Danko, Martin
    Bajuk-Bogdanovic, Danica
    Todorovic-Markovic, Biljana
    CERAMICS INTERNATIONAL, 2019, 45 (14) : 17006 - 17013
  • [39] Bridging biological and food monitoring: A colorimetric and fluorescent dual-mode sensor based on N-doped carbon dots for detection of pH and histamine
    Zhang, Xiaoran
    Wang, Jing
    Hasan, Elias
    Sun, Xincheng
    Asif, Muhammad
    Aziz, Ayesha
    Lu, Wenjing
    Dong, Chuan
    Shuang, Shaomin
    JOURNAL OF HAZARDOUS MATERIALS, 2024, 470
  • [40] Dual-Ion-Mode MALDI MS Detection of Small Molecules with the O-P,N-Doped Carbon/Graphene Matrix
    Zhao, Huifang
    Li, Yanqiu
    Wang, Jie
    Cheng, Miao
    Zhao, Zheng
    Zhang, Huinian
    Wang, Congwei
    Wang, Junying
    Qiao, Yan
    Wang, Junzhong
    ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (43) : 37732 - 37742