A reaction study for Al-Ni2O3 nano self-exothermic materials

被引:0
|
作者
Yu, Wenzhen [1 ]
Gao, Yimin [1 ]
Wang, Yiran [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian, Peoples R China
基金
中国博士后科学基金;
关键词
Ni2O3; Al powder; Nano self-exothermic materials; Oxide reaction; BEHAVIOR; NI;
D O I
10.1016/j.ceramint.2023.12.038
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Cast -infiltration has emerged as a prevalent technique for fabricating metal matrix composites. Studying Al-Ni(2)O(3 )nano self-exothermic materials proves valuable, given their potential to enhance metal matrix composites' casting defect resolution as nano self-exothermic materials. This study analyzes reaction characteristics, mechanisms, parameter-exothermic characteristic relationships, moderating methods, and their respective influences. Reaction products from Al-Ni(2)O(3)nano self-exothermic materials include Al2O3, AlNix, and trace amounts of Al. The closer the powder's composition ratio aligns with equilibrium stoichiometry, the smaller the heat released during self-exothermic reactions; smaller powder particles result in larger self-exothermic reaction heat releases and lower reaction temperatures, with reactions ceasing when exceeding the critical size (l > 40 mu m). Different reaction environments also impact reaction products, with comparatively lesser effects on reaction temperatures. By modulating powder parameters and reaction conditions, Al-Ni(2)O(3 )nano self-exothermic materials' reaction temperature can be adjusted between 609 degrees C and 900 degrees C. Correspondingly, the reaction exotherm ranges from 232 J/g to 1560 J/g, providing heat compensation for subsequent composite material casting.
引用
收藏
页码:6909 / 6920
页数:12
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