One-step fabrication of vanadium-doped CoFe PBA nanosheets for efficient oxygen evolution reaction

被引:5
|
作者
Huang, Yin [1 ]
Pan, Yaoyao [1 ]
Huang, Xiaoyu [1 ]
Xu, Guangzheng [1 ]
Wang, Xiuhua [1 ]
机构
[1] Anhui Normal Univ, Key Lab Electrochem Clean Energy,Anhui Higher Educ, Coll Chem & Mat Sci,Anhui Lab Mol Based Mat, Key Lab Funct Mol Solids,Minist Educ, Wuhu 241000, Peoples R China
关键词
BIFUNCTIONAL ELECTROCATALYST; NI;
D O I
10.1039/d3dt01629c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Finding effective and affordable non-noble metal catalysts is one of the most important yet difficult tasks because of the sluggish kinetics of the oxygen evolution reaction (OER). Therefore, we synthesized vanadium-doped CoFe PBA nanosheets on nickel foam in a single step to change the electronic structure with metal doping. The sheet structure facilitates charge transfer, while vanadium doping modifies the electronic structure to enhance the catalytic activity. With just a 229 mV overpotential needed in the OER reaction to reach 10 mA cm(-2), the as-synthesised electrocatalyst demonstrates high electrocatalytic activity. The produced electrocatalyst can operate at a current density of 10 mA cm(-2) for 12 h, and it displays outstanding stability even at a high OER current density of 100 mA cm(-2) for 12 h. This study will contribute to the development of efficient and affordable non-noble metal-based electrocatalysts.
引用
收藏
页码:11297 / 11302
页数:6
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