Enhanced corrosion inhibition effect of sodium tartrate on copper in potable water

被引:2
|
作者
Sudhakaran, Ramasamy [1 ,2 ]
Deepa, Thiagarajan [2 ,3 ]
Thirumavalavan, Munusamy [4 ]
Sabarimuthu, Sharmila Queenthy [4 ]
Babu, Sellamuthu [1 ,2 ]
Asokan, Thayuman [1 ,2 ]
Almansour, Abdulrahman I. [5 ]
Raja, Pandian Bothi [6 ]
Perumal, Karthikeyan [7 ]
机构
[1] Govt Arts Coll, PG & Res Dept Chem, Tiruchirappalli 620022, Tamil Nadu, India
[2] Bharathidasan Univ, Tiruchirappalli 620024, Tamil Nadu, India
[3] Govt Arts Coll, PG & Res Dept Chem, Karur 639005, Tamil Nadu, India
[4] Saveetha Engn Coll, Dept Chem, Chennai 602105, Tamil Nadu, India
[5] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
[6] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia
[7] Ohio State Univ, Dept Chem & Biochem, 151 W Woodruff Ave, Columbus, OH 43210 USA
关键词
Corrosion; Copper; Electrochemical studies; SEM; EDAX; AFM; Water contact angle; CARBON-STEEL; ACID;
D O I
10.1016/j.jksus.2023.102921
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In this study we have reported sodium tartrate (ST) and Zn2+ as the potential mixed corrosion inhibitors for copper corrosion in drinking water, by using electrochemical impedance and polarization techniques. The results of potentio-dynamic polarization indicated that sodium tartrate could be used as mixed type inhibitor with Zn2+. ST was found to be 92% effective for slowing down both the anodic and cathodic reaction rates. It was additionally found that ST could coat the surface of copper to prevent it from conducting electricity. As the inhibitor concentration increased, the stability of the formed protective layer was also improved. The results obtained from studies like SEM, EDAX, AFM, and water contact angle clearly indicated the development of a barrier by inducing the lotus effect on copper surface. The water contact angle measurement results suggested that the coating formed in the presence of inhibitor was superhydrophobic, and the surface was homogeneous.(c) 2023 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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页数:7
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