Crystal structure and Hirshfeld-surface analysis of a monoclinic polymorph of 2-amino-5-chlorobenzophenone oxime at 90 K

被引：0
|
作者：
Geetha, Doreswamy [1 ]
Kavitha, Channappa N. [2 ]
Divakara, Thayamma R. [3 ]
Basavaraju, Yeriyur B. [1 ]
Yathirajan, Hemmige S. [1 ]
Parkin, Sean [4 ]
机构：
[1] Univ Mysore, Dept Studies Chem, Mysuru 570006, India
[2] Govt Sci Coll, Dept Chem, Hassan 573201, India
[3] CT John Inst Technol, Bengaluru 560083, India
[4] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
基金：
美国国家科学基金会;
关键词：
crystal structure; benzophenone oxime; polymorph; Hirshfeld surface; 1,4-BENZODIAZEPINES; QUINAZOLINES; DERIVATIVES;
D O I：
10.1107/S2056989023004668
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The synthesis and crystal structure of a monoclinic polymorph of 2-amino-5-chlorobenzophenone oxime, C13H11ClN2O, are presented. The molecular conformation results from twisting of the phenyl and 2-amino-5-chloro benzene rings attached to the oxime group, which subtend a dihedral angle of 80.53 (4)degrees. In the crystal, centrosymmetric dimers are formed as a result of pairs of strong O-H center dot center dot center dot N hydrogen bonds. A comparison is made to a previously known triclinic polymorph, including differences in atom-atom contacts obtained via a Hirshfeld-surface analysis.
引用
收藏
页码：610 / +
页数：8
相关论文
共 50 条
  • [41] Crystal structure and Hirshfeld analysis of 2-(5-bromothiophen-2-yl)acetonitrile
    Pappenfus, Ted M.
    Wood, Tiana L.
    Morey, Joseph L.
    Wilcox, Wyatt D.
    Janzen, Daron F.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 189 - +
  • [42] Crystal structure and Hirshfeld surface analysis of N-(5-iodo-4-phenylthiazol-2-yl)acetamide
    Herrera-Espana, Angel D.
    Aguilera-Gonzalez, Jesus
    Mena-Rejon, Gonzalo J.
    Hernandez-Ortega, Simon
    Caceres-Castillo, David
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 : 717 - +
  • [43] Crystal structure and Hirshfeld surface analysis of (E)-3-(benzylideneamino)-5-phenylthiazolidin-2-iminium bromide
    Duruskari, Gulnara Sh
    Akkurt, Mehmet
    Mammadova, Gunay Z.
    Chyrka, Taras
    Maharramov, Abel M.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 427 - +
  • [44] (E)-{[(Butylsulfanyl)methanethioyl]amino}(4-meth-oxybenzylidene)amine: crystal structure and Hirshfeld surface analysis
    Rusli, Aqilah Fasihah
    Kwong, Huey Chong
    Crouse, Karen A.
    Jotani, Mukesh M.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 208 - +
  • [45] Crystal structure and Hirshfeld surface analysis of ethyl (E)-4-[(4-hydroxy-3-methoxy-5-nitrobenzylidene)amino]benzoate
    Victoria, Antony Samy
    Sivajeyanthi, Palaniyappan
    Elangovan, Natarajan
    Balasubramani, Kasthuri
    Kolochi, Thathan
    Thanikasalam, Kanagasabapathy
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1079 - +
  • [46] Synthesis, structure, Hirshfeld surface analysis, and computational studies of 2-amino-5-nitropyridine-2,4-dinitrophenol cocrystal
    Sivaraman, Shanmugam
    Balakrishnan, Chellakarungu
    Suppuraj, Palusamy
    Meenakshisundaram, Subbiah
    STRUCTURAL CHEMISTRY, 2023, 34 (01) : 239 - 249
  • [47] Synthesis, structure, Hirshfeld surface analysis, and computational studies of 2-amino-5-nitropyridine-2,4-dinitrophenol cocrystal
    Shanmugam Sivaraman
    Chellakarungu Balakrishnan
    Palusamy Suppuraj
    Subbiah Meenakshisundaram
    Structural Chemistry, 2023, 34 : 239 - 249
  • [48] A Hirshfeld surface analysis, crystal structure and physicochemical studies of a new Cd(II) complex with the 2-amino-4-methylpyrimidine ligand
    Klai, Kacem
    Kaabi, Kamel
    Kaminsky, Werner
    Jelsch, Christian
    Lefebvre, Frederic
    Ben Nasr, Cherif
    JOURNAL OF MOLECULAR STRUCTURE, 2017, 1128 : 378 - 384
  • [49] Crystal structure and Hirshfeld surface analysis of the 1:3 adduct of tetraaquatrinitratoneodymium(III) with 3-amino-1,2,4-triazine
    Sangeetha, Ramalingam
    Balasubramani, Kasthuri
    Kavitha, Savaridasson Jose
    Hemamalini, Madhukumar
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1309 - +
  • [50] Synthesis, Hirshfeld Surface, FTIR Analysis and Single Crystal X-Ray Structure of 2-Amino-3-Hydroxypyridinium Saccharinate
    S. D. Kanmazalp
    M. Sagher
    N. Dege
    H. Içbudak
    Journal of Structural Chemistry, 2023, 64 : 1137 - 1146
12345