Sustainability of kraft pulp mills: Bleaching technologies and sequences with reduced water use

被引:9
|
作者
Sousa, A. M. [1 ]
Pinto, I. S. S. [2 ]
Machado, L. [2 ]
Gando-Ferreira, L. [1 ]
Quina, M. J. [1 ]
机构
[1] Univ Coimbra, Dept Chem Engn, CIEPQPF, Rua Silvio Lima, Polo 2-Pinhal Marrocos, P-3030790 Coimbra, Portugal
[2] Inst Invest Floresta & Papel, RAIZ, Quinta Sao Francisco, Apartado 15, P-3801501 Aveiro, Portugal
关键词
Sustainability; Pulp mills; Water reduction; Bleaching; Elemental chlorine free; LIFE-CYCLE ASSESSMENT; CHLORINE DIOXIDE; HEXENURONIC ACID; HOT; DELIGNIFICATION; EFFLUENT; OXYGEN; ECF; AOX;
D O I
10.1016/j.jiec.2023.05.033
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Kraft pulp industry is a relevant industrial sector in many countries with a considerable social, economic, and environmental impact. Thus, sustainability is the adequate framework to address this activity sector. This work presents a review of the literature, with a particular focus on the bleaching area and its relevance in reducing water use. The sustainability reports of the most prominent pulp and paper companies were analyzed, considering their specific water utilization and the sustainability targets they have outlined. The most industrially applied bleaching sequences were also addressed and the stages of the state-of-the-art sequences were analyzed (elemental chlorine free - ECF bleaching). Moreover, in this review, a detailed analysis of a sequence used on an industrial scale was carried out, highlighting the washing steps and the measures that are taken to minimize water use. The main limitations to the minimization of water use were identified, being deposit formation the major problem. Measures to overcome these limitations, as well as future perspectives were discussed. Due to the shortage of freshwater nearby some pulp and paper production sites, there will continue to be great pressure in the future to reduce water utilization, especially in the bleaching area.& COPY; 2023 The Author(s). Published by Elsevier B.V. on behalf of The Korean Society of Industrial and Engineering Chemistry. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
引用
收藏
页码:58 / 70
页数:13
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