Catalytic System-Controlled Regioselective 1,2-and 1,4-Carboannulations of [60]Fullerene

被引：1

作者：

Liu, Tong-Xin ^{[1
]}

Ru, Yifei ^{[1
]}

Guo, Wenyue ^{[1
]}

Ma, Nana ^{[1
]}

Yang, Panting ^{[1
]}

Li, Xiaojun ^{[1
]}

Zhang, Pengling ^{[1
]}

Bi, Jingjing ^{[1
]}

Zhang, Guisheng ^{[1
]}

机构：

[1] Henan Normal Univ, Sch Chem & Chem Engn, Key Lab Green Chem Media & React, Minist Educ, Xinxiang 453007, Henan, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 13期

基金：

中国国家自然科学基金;

关键词：

FULLERENES; CYCLOADDITION; DIASTEREO; C-60;

D O I：

10.1021/acs.orglett.4c00482

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selective functionalization of fullerenes is an important but challenging topic in fullerene chemistry and synthetic chemistry. Here we present the first example of catalytic system-controlled regioselective 1,2- and 1,4-addition reactions for the flexible and efficient synthesis of novel 1,2- and 1,4-carbocycle-fused fullerenes via a palladium-catalyzed decarboxylative carboannulation process.

引用

页码：2552 / 2557

页数：6

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