Electrical and optical properties of poly(acrylamide-co-acrylic acid) based polymer electrolytes containing water-soluble potassium iodide salt

被引：2
|
作者：
Lee, Y. C. [1 ]
Buraidah, M. H. [1 ,3 ]
Woo, H. J. [1 ]
Teo, L. P. [2 ]
机构：
[1] Univ Malaya, Ctr Ion Univ Malaya, Fac Sci, Dept Phys, Kuala Lumpur, Malaysia
[2] Tunku Abdul Rahman Univ Management & Technol, Fac Appl Sci, Dept Phys Sci, Jalan Genting Kelang, Kuala Lumpur, Malaysia
[3] Univ Malaya, Ctr Ion Univ Malaya, Fac Sci, Dept Phys, Kuala Lumpur 50603, Malaysia
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2023年 / 760卷 / 01期
关键词：
Fourier transform infrared (FTIR) spectroscopy; ionic conductivity; Poly(acrylamide-co-acrylic acid; potassium iodide; solid polymer electrolyte; SENSITIZED SOLAR-CELLS; ION-TRANSPORT; POLYACRYLAMIDE; KI;
D O I：
10.1080/15421406.2023.2166135
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Poly(acrylamide-co-acrylic acid) (PAAm-PAA) based solid polymer electrolytes (SPEs) containing potassium iodide (KI) have been prepared. The complexation between PAAm-PAA and KI has been identified through the position changes at the asymmetric NH2 stretching and CH2 stretching; and the intensities changes at the amide (C = O, C-N) and carboxylate (COO-) bands using Fourier transform infrared (FTIR) spectroscopy. PAAm-PAA film exhibits a room temperature (RT) ionic conductivity of (8.8 +/- 0.8) x 10(-11) S center dot cm(-1) which increases to maximum at (4.0 +/- 0.5) x 10(-7) S center dot cm(-1) with 45 wt.% KI addition. The conductivity-temperature dependence studies of all samples followed the Arrhenius rule.
引用
收藏
页码：51 / 59
页数：9
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